Abstract
N-Trimethylsilylamides react with aminohalogenoboranes in nearly quantitative yield to monomeric amido(bis)aminoboranes. From the reaction of N-substituted acylamides with bis(amino)halogenoboranes and dialkoxyhalogenoboranes respectively and triethylamine corresponding amido-bis(amino)-and amido-bis(alkoxy)boranes were obtained in high yields. In certain cases equilibria between monomeric and dimeric forms are observed.1H,11R, and19F.-n.m.r. spectra, mass spectra and characteristic i.r. group frequencies are reported.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literatur
V. A. Dorokhov, L. I. Lavrinovich, I. P. Yakovlev undB. M. Mikhailov, Zh. Obsh. Khim.41, 2501 (1971).
B. M. Mikhailov undV. A. Dorokhov, Izv. Akad. Nauk SSSR, Otd. Khim.1970, 1446.
B. M. Mikhailov, V. A. Dorokhov, V. S. Bogdanov, I. P. Yakovlev undA. P. Naumov, Dokl. Akad. Nauk SSSR194, 595 (1970).
W. Maringgele undA. Meller, Z. anorg. allg. Chem. (im Druck).
W. Maringgele undA. Meller, z. anorg. allg. Chem. (im Druck).
H. Nöth, Z. Naturforsch.16 b, 618 (1961).
A. B. Burg undR. I. Kuljian, J. Amer. Chem. Soc.72, 3103 (1950).
S. Sijushi undS. Witz, J. Amer. Chem. Soc.79, 2447 (1957).
E. A. V. Ebsworth undH. J. Emeleus, J. Chem. Soc.1958, 2150.
M. Fukui, K. Itoh undY. Ishii, J. Chem. Soc. Perkin Trans II1972, 1043.
M. T. Rogers undI. C. Woodbrey, J. Phys. Chem.66, 540 (1962).
H. Kessler, Angew. Chem.82, 237 (1970).
H. Kessler, Ann. Chem.708, 57 (1967).
H. Kessler, Angew. Chem.80, 201 (1968).
A. J. R. Bourn, D. G. Gillies undE. W. Randall, Tetrahedron22, 1825 (1966).
L. A. LaPlanche undM. T. Rogers, J. Amer. Chem. Soc.86, 337 (1964).
L. A. LaPlanche undM. T. Rogers, J. Amer. Chem. Soc.85, 3782 (1963).
E. Wiberg undU. Kruerke, Z. Naturforsch.8 b, 608 (1953).
R. Köster, Angew. Chem.72, 626 (1960).
A. B. Burg undC. L. Randolph, J. Amer. Chem. Soc.73, 953 (1951).
A. Dornon undH. H. Gehrt, Z. anorg. allg. Chem.294, 81 (1958).
E. Wiberg undK. Schuster, Z. anorg. allg Chem.213, 77 (1933).
H. Nöth, W. A. Dorokhov undF. Pfab, Z. anorg. allg. Chem.318, 293 (1962).
W. Gerrard, M. F. Lappert undC. A. Pearce, J. Chem. Soc.1957, 381.
H. Nöth undW. Lukas, Chem. Ber.95, 1505 (1962).
J. Goubeau, M. Rahtz undH. J. Becher, Z. anorg. allg. Chem.,275, 161 (1954).
R. J. Brotherton, A. L. McCloskey, L. L. Petterson undH. Steinberg, J. Amer. Chem. Soc.82, 6242 (1960).
K. Niedenzu, H. Beyer undJ. W. Dawson, Inorg. Chem.1, 738 (1962).
A. Finch, P. J. Gardner, E. J. Pearn undG. B. Watts, Trans. Faraday Soc.63 1880 (1967).
Author information
Authors and Affiliations
Additional information
11. Mitt.:W. Maringgele undA. Meller, Chem. Ber., eingereicht.
Rights and permissions
About this article
Cite this article
Meller, A., Maringgele, W., Beer, G. et al. Umsetzung von Metall- und Metalloidverbindungen mit mehrfunktionellen Molekülen, 12. Mitteilung. Monatshefte für Chemie 108, 1279–1293 (1977). https://doi.org/10.1007/BF01046441
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF01046441