Abstract
The structure of thep-t-butyldihomooxacalix[4]arene triethylamine (1 : 2 complex has been determined by X-ray crystallography. Crystals are monoclinic, space groupCc,a = 22.821(3),b = 15.257(3),c = 16.365(2) Å,β = 97.44(1)°,V = 5650(1) Å3,Z = 4,D calc = 1.03 g cm−3. One triethylamine (Et3N) molecule has one of its ethyl groups pointing inside the cavity of a calixarene molecule; its nitrogen atom is directed exo to this calixarene molecule and is involved in a hydrogen bond with one of the hydroxy groups of a neighbouring calixarene molecule. This scheme leads to columns of alternating host and guest molecules. The other Et3N molecule is in the interhost space. This feature allows us to define the title compound as a complex/clathrate hybrid.
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K. Suzuki, A. E. Armah, S. Fujii, K. Tomita, Z. Asfari and J. Vicens:Chem. Lett. 1699 (1991).
Z. Asfari, J. M. Harrowfield, M. I. Ogden, J. Vicens and A. H. White:Angew. Chem. Int. Ed. Engl. 30, 854 (1991).
M. Perrin and S. Lecocq:J. Crystallogr. Spectrosc. Res. 22, 419 (1992). A. E. Armah, K. Suzuki, S. Fujii, K. Tomita, Z. Asfari and J. Vicens:Acta Crystallogr. C48, 1474 (1992).
C. D. Gutsche, M. Iqbal and I. Alam:J. Am. Chem. Soc. 109, 4314 (1987).
B. A. Frenz: ‘The Enraf-Nonius CAD 4 SDP, A real-time system for concurrent X-ray data collection and crystal structure determination’ inComputing in Crystallography, H. Schenk, R. Olthof-Hazekamp, H. van Konningsveld and G. C. Bassi (Eds) Delft University Press, Delft, The Netherlands p. 64 (1978).
P. Main, S. J. Fiske, S. E. Hull, L. Lessinger, G. Germain, J. P. Declercq and M. M. Woolfson:MULTAN 80. A system of computer programs for the automatic solution of crystal structures from X-Ray diffraction data. University of York, England and Louvain, Belgium (1980).
G. M. Sheldrick:SHELX, Computer Program for Crystal Structure determination. University of Cambridge, England (1976).
International Tables for X-Ray Crystallography. Vol. IV. Kynoch Press, Birmingham, England (1974) pp. 72–98. Dist. Kluwer Academic Publishers, Dordrecht and Boston.
G. D. Andreetti, Y. Nakamoto and S. I. Ishida:J. Incl. Phenom. 10, 241 (1991).
M. Czugler, S. Tisza and G. Speier:J. Incl. Phenom. 11, 323 (1991).
H. B. Gray:Electrons and Chemical Bonding. W. A. Benjamin INC. New York, Amsterdam (1964).
E. Weber and H. P. Josel:J. Incl. Phenom. 1, 79 (1983).
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Supplementary data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82144 (8 pages).
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Bavoux, C., Perrin, M. A hydrogen bond between a calixarene (as host and its guest: Crystal and molecular structure of thep-t-butyldihomooxacalix[4]arene : Triethylamine (1 : 2) complex/clathrate. J Incl Phenom Macrocycl Chem 14, 247–256 (1992). https://doi.org/10.1007/BF01045984
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DOI: https://doi.org/10.1007/BF01045984