Abstract
The effect of temperature on the UV-visible spectra of the acid forms of methyl orange and methyl yellow in the presence of α- andβ-cyclodextrins was analysed in terms of 1 : 1 inclusion processes. Three inclusion processes were considered for each azo dye/cyclodextrin system. The processes are the apparent inclusion process, the ammonium inclusion process, and the azonium inclusion process. The values of ΔH 0 and ΔS 0 are reported for each process. The inclusion complexes of the ammonium tautomer are more stable than those of the azonium tautomer and α-cyclodextrin inclusion complexes are more stable than those ofβ-cyclodextrin. The inclusion processes resulted in a shift in the position of the tautomeric equilibrium of an azo dye. A significant color fading was observed in α-cyclodextrin/methyl yellow solutions. No measurable changes in the absorbances were observed in the case of azo dye solutions containing γ-cyclodextrin.
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Tawarah, K.M. A thermodynamic study of the inclusion processes of α- andβ-cyclodextrins with the acid forms of methyl orange and methyl yellow. J Incl Phenom Macrocycl Chem 14, 195–204 (1992). https://doi.org/10.1007/BF01045980
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DOI: https://doi.org/10.1007/BF01045980