Abstract
The results of studies on the wettability and contact interaction of rare-earth (REE) oxides and aluminium oxide (for comparison) with metallic melts are presented. Proceeding from analysis of the data obtained, a mechanism of interaction of metallic melts with rare-earth element oxides is proposed, based on the interaction of the metallic melt components with the cationic and the anionic sublattice of the oxides. The necessity to take into account the interaction of the melt metal with the cationic sublattice of oxide is determined by a high chemical affinity of the REE for quite a number of metals and by specific features of the structure of the surface of the oxides.
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References
Ju. V. Naidich, “Contact Phenomena in Metallic Melts” (Naukova dumka, Kiev, 1972) pp. 196.
Mukai Kusuhiro,Ceram. Jpn 10 (1975) 558.
D. Beruto, L. Barco andA. Rasserone, “Refractory oxides, high temperature solid-gas and solid-liquid behavior”. Oxide and oxide films, Vol. 6 (New York, Basel, 1981) pp. 1–83.
F. Delannay, L. Froyen andA. Deruttere,J. Mater. Sci. 22 (1987) 1.
W. A. Weyl,J. Soc. Glass Technol. 32 (148) (1948) 247.
D. T. Livey andP. Murray, “The Wetting Properties of Solid Oxides and Carbides by Liquid Metals”, De Re Metallica Plansee Seminar (Reutte/Tyrol. Metallwerk Plansee, 1955) p. 375.
C. E. Holley, E. S. Huber andF. B. Baker, “The entalpies, entropies and Gibbs energies of formation of rare-earth oxides”, in “Progress in Science and Technology of Rare-earths”, Vol. 3 (Pergamon, New York, 1968) pp. 343–433.
C. E. Wicks andF. E. Block, “Thermodynamic properties of 65 elements-their oxides, carbides and nitrides”, (US Department of the Interior, Moscow Metaluzgu, 1965).
Ju. V. Naidich andV. S. Zhuravljov,Zavod. Labor. (4) (1971) 18.
S. P. Gordienko andV. V. Fenochka,Zh. Fiz. Khim. 46 (1972) 2341.
R. E. Tressler andT. L. Moore,Metal Eng. Q. 11 (1970) 16.
Ju. V. Naidich andV. S. Zhuravljov,Ogneupory (1) (1974) 50.
H. Nocholas, T. H. Valentine andM. S. Waile,J. Mater. Sci. 15 (1980) 2197.
Sugino Shiglaki, Satoh Yoshitano, Hagiwara Hasalo,Bull. Osaka Univ. 1717(1) (1968) 185.
V. S. Sudavstova, G. I. Batalin, F. F. Kuznetsov andI. G. Bondarenko,Ukr. Khim. Zh. 53 (1987) 498.
I. G. Kulagina, A. P. Bajanov andN. M. Kulagin,Izv. AN SSSR Metally (3) (1985) 211.
E. A. Beloborodova,Zh. Fiz. Khim VIII (6) (1978) 1769.
V. N. Nizhenko andL. I. Floka, “Surface tension of liquid metals and alloys” (Metalurgia, Moscow, 1981) 208 pp.
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Naidich, J.V., Zhuravljov, V.S. & Frumina, N.I. Wetting of rare-earth element oxides by metallic melts. J Mater Sci 25, 1895–1901 (1990). https://doi.org/10.1007/BF01045739
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DOI: https://doi.org/10.1007/BF01045739