Summary
Diphenylmethane underwent oxidative coupling in the presence of di-t-butyl peroxide and formed 1,1,2,2-tetraphenylethane. This coupling reaction resulted in the formation of a copolymer of diphenylmethane andp-xylene. The new copolymer was soluble in common organic solvents and had a molecular weight of 32,000 (polystyrene base).
Similar content being viewed by others
References
Korshak V V, Sosin S L, Alekseeva V L (1961) J Polym Sci 52: 213.
Kortüm G, Dreesen G (1951) Chem Ber 84; 182.
Toda F, Tanaka K, Wang Yu, Lee G-H (1986) Chem Let: 109.
Author information
Authors and Affiliations
Additional information
On leave from Cosmo Oil Co., Japan, under a contract with the Japan International Cooperation Agency
Rights and permissions
About this article
Cite this article
Inoue, M., Cantua, S., Medrano, F. et al. Copolymerization of diphenylmethane andp-xylene by oxidative coupling. Polymer Bulletin 28, 29–32 (1992). https://doi.org/10.1007/BF01045634
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01045634