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Synthesis of polymers with cryptand-like units via radical cyclopolymerization of diacrylate and dimethacrylate derived from diaza-12-crown-4, and the binding property for lithium ion

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Summary

Polymers with cryptand-like units have been obtained by the radical cyclopolymerization of 4,10-bis(acryloyloxyethyl)- and 4,10-bis(methacryloyloxyethyl)-1,7-dioxa-4,10-diazacyclododecane. The polymers consist of only bicyclic constitutional units, though having fairly low molecular weight. In the complexation with alkali-metal ions, the participation of the cavity effect for Li+ ion and the cooperative effect of neighbouring ligands for the larger ions is a characteristic of the polymers, thereby giving high binding ability for every ion, but low selectivity.

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Authors and Affiliations

  1. Department of Industrial Chemistry, Asahikawa National College of Technology, Shunkodai, 071, Asahikawa, Japan

    Masahiro Miyajima & Katsuyuki Tsuda

  2. Department of Chemical Process Engineering, Faculty of Engineering, Hokkaido University, Kita-ku, 060, Sapporo, Japan

    Toyoji Kakuchi & Kazuaki Yokota

Authors
  1. Masahiro Miyajima
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  2. Katsuyuki Tsuda
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  3. Toyoji Kakuchi
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  4. Kazuaki Yokota
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Miyajima, M., Tsuda, K., Kakuchi, T. et al. Synthesis of polymers with cryptand-like units via radical cyclopolymerization of diacrylate and dimethacrylate derived from diaza-12-crown-4, and the binding property for lithium ion. Polymer Bulletin 28, 23–28 (1992). https://doi.org/10.1007/BF01045633

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  • DOI: https://doi.org/10.1007/BF01045633

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