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Stereoselective anionic ring opening polymerization of 1,1-dimethyl-1-silacyclobutene

Characterization of poly(1,1-dimethyl-1-sila-cis-but-2-ene)

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Summary

Stereoselective anionic ring opening polymerization of 1,1-dimethyl-1-silacyclobutene co-catalyzed byn-butyllithium and hexamethylphosphoramide (HMPA) in THF at -78°C yields predominantly poly(1,1-dimethyl- 1-sila-cis-but-2-ene). The polymer has been characterized by1H,13C,29Si NMR spectroscopy, gel permeation chromatography (GPC), thermogravimetric analysis (TGA) and elemental analysis.

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Authors and Affiliations

  1. D. P. and K. B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA

    Macrus Theurig & William P. Weber

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  1. Macrus Theurig
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  2. William P. Weber
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Theurig, M., Weber, W.P. Stereoselective anionic ring opening polymerization of 1,1-dimethyl-1-silacyclobutene. Polymer Bulletin 28, 17–21 (1992). https://doi.org/10.1007/BF01045632

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  • DOI: https://doi.org/10.1007/BF01045632

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