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Molecular engineering of liquid crystalline polymers by living polymerization

21. Synthesis and characterization of poly{3-[(4-cyano-4′-biphenyl)oxy]propyl vinyl ether} macromonomers

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Summary

This paper describes the synthesis and characterization of poly{3-[4-cyano-4′-biphenyl)oxy]propyl vinyl ether} [poly(6-3)] macromonomers obtained by the functionalization of the growing chain end of the corresponding living polymer obtained by the initiation of the cationic polymerization of 3-[4-cyano-4′-biphenyl)oxy]propyl vinyl ether with CF3SO3H/S(CH3)2, with 2-hydroxy ethyl methacrylate [poly(6-3)-I], 2-[2-(2-allyloxyethoxy)ethoxy]ethanol [poly(6-3)-II] and 10-undecen-1-ol [poly(6-3)-III].

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Authors and Affiliations

  1. Department of Macromolecular Science, Case Western Reserve University, 44106, Cleveland, OH, USA

    Virgil Percec, Myongsoo Lee & Dimitris Tomazos

Authors
  1. Virgil Percec
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  2. Myongsoo Lee
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  3. Dimitris Tomazos
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Additional information

Part 20: V. Percec and M. Lee, J. Mater. Chem., submitted

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Percec, V., Lee, M. & Tomazos, D. Molecular engineering of liquid crystalline polymers by living polymerization. Polymer Bulletin 28, 9–15 (1992). https://doi.org/10.1007/BF01045631

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  • DOI: https://doi.org/10.1007/BF01045631

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