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Molecular associations of [2.2]paracyclophanearylhydrazones with organic acceptors, VIII

Molekulare Assoziation von [2.2]Paracyclophanarylhydrazonen mit organischen Akzeptoren, 8. Mitt.

  • Organische Chemie Und Biochemie
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Summary

Molecular complexes of mono and disubstituted [2.2]paracyclophanehydrazones with organic acceptors have been studied by means of thermodynamic and spectroscopic properties. Furthermore, the enhancement of the donor strength, induced by the hydrazono group, is viewed in the light of substituent as well as transannular effects.

Zusammenfassung

Es wurden Molekülkomplexe von mono- und disubstituierten [2.2]Paracyclophanarylhydrazonen mit organischen Akzeptoren mittels thermodynamischer und spektroskopischer Methoden untersucht. Zusätzlich wird der Anstieg in der Donorstärke, der von der Hydrazonogruppe induziert wird, im Hinblick auf Substituenten- und auch transannulare Effekte diskutiert.

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Authors and Affiliations

  1. Dipartimento di Scienze dei Materiali e della Terra, Università degli Studi di Ancona, I-60131, Ancona, Italy

    Paolo Bruni, Carla Conti, Elisabetta Giorgini & Giorgio Tosi

  2. Institut für Organische Chemie, Universität Braunschweig, D-W-3300, Braunschweig, Federal Republic of Germany

    Henning Hopf & Jorg Hillmer

Authors
  1. Paolo Bruni
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  2. Carla Conti
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  3. Elisabetta Giorgini
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  4. Giorgio Tosi
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  5. Henning Hopf
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  6. Jorg Hillmer
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Bruni, P., Conti, C., Giorgini, E. et al. Molecular associations of [2.2]paracyclophanearylhydrazones with organic acceptors, VIII. Monatsh Chem 123, 73–80 (1992). https://doi.org/10.1007/BF01045299

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  • DOI: https://doi.org/10.1007/BF01045299

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