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Preparation of plasma-polymerized membranes from fluoroalkyl acrylates and methacrylates and gas permeability through the membranes

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Summary

Plasma-polymerized membranes were prepared from fluoroalkyl acrylates and methacrylates by two different directions of monomer injection and the permeation rates of O2 and n2 through the membranes were investigated. The chemical structure and composition of the plasmapolymerized membranes varied significantly by the direction of monomer injection. The optimum plasma conditions to yield maximum gas separation characteristics was obtained by the remote plasma excitation at the W/FM value of 20 J/mg, where W is the discharge power, F is the monomer flow rate and M is the molecular weight of the monomer.

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Authors and Affiliations

  1. Department of Chemical Engineering, Yamaguchi University, Ube, 755, Yamaguchi, Japan

    Hidetoshi Kita, Masanobu Shigekuni, Kazuhiro Tanaka & Ken-ichi Okamoto

  2. Osaka Municipal Technical Research Institute, Morinomiya, Joto-ku, 536, Osaka, Japan

    Isao Kawafune

Authors
  1. Hidetoshi Kita
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  2. Masanobu Shigekuni
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  3. Isao Kawafune
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  4. Kazuhiro Tanaka
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  5. Ken-ichi Okamoto
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Kita, H., Shigekuni, M., Kawafune, I. et al. Preparation of plasma-polymerized membranes from fluoroalkyl acrylates and methacrylates and gas permeability through the membranes. Polymer Bulletin 21, 371–376 (1989). https://doi.org/10.1007/BF01045172

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  • DOI: https://doi.org/10.1007/BF01045172

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