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Dioxomolybdenum(VI) complexes of dibasic tridentate Schiff bases having the HO-N-OH donor system

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Summary

The synthesis and structural features of some dibasictridentate Schiff base complexes of dioxomolybdenum of the type MoO2L and MoO2L·DMSO are described. The ligands, LH2 were derived by the condensation of 2-hydroxy-1-naphthaldehyde, 2,4-pentanedione and 2-hydroxyacetophenone with glycine or β-alanine. The new complexes were characterized by elemental analysis, conductance, molecular weight and magnetic measurements. Based on i.r.,1H n.m.r.,13C n.m.r. studies, a pseudooctahedral and octahedral structure is proposed for MoO2L and MoO2L·DMSO respectively.

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Authors and Affiliations

  1. Department of Chemistry, University of Rajasthan, 302004, Jaipur, India

    Neeta Kanoongo, Ranvir Singh & Jagdish P. Tandon

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  1. Neeta Kanoongo
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  2. Ranvir Singh
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  3. Jagdish P. Tandon
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Kanoongo, N., Singh, R. & Tandon, J.P. Dioxomolybdenum(VI) complexes of dibasic tridentate Schiff bases having the HO-N-OH donor system. Transition Met Chem 14, 221–223 (1989). https://doi.org/10.1007/BF01043800

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  • DOI: https://doi.org/10.1007/BF01043800

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