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Structural studies of 4-benzamido-1-o-aminoacetophenone-3-thiosemicarbazone complexes

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Summary

Complexes of CuII, NiII, CoII, ZnII, CdII and HgII with 4-benzamido-1-o-aminoacetophenone-3-thiosemicarbazone (H2BATS) are reported and have been characterized by elemental analyses, molar conductivities, magnetic moments, spectral (visible, i.r.) and thermal (d.t.a., t.g., d.t.g.) measurements. I.r. spectra show that H2BATS behaves as a dianionic, monoanionic or neutral tetradentate ligand or as a monoanionic tridentate ligand. [Cu2(H2BATS)Cl2]·2H2O and [Cu2(H2BATS)Ac2]·2H2O complexes are diamagnetic while [Co(HBATS)OH]·2H2O and [Ni(HBATS)OH]·2H2O are octahedral. All the complexes are non-electrolytes. Generally, the solid metal acetate complexes have a unique decomposition exotherm profile which can be used as a rapid and sensitive tool for the detection of acetate-containing complexes.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt

    Gaber M. Abu El-Reash, Kamal M. Ibrahim & Tawfik H. Rakha

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  1. Gaber M. Abu El-Reash
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  2. Kamal M. Ibrahim
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  3. Tawfik H. Rakha
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Abu El-Reash, G.M., Ibrahim, K.M. & Rakha, T.H. Structural studies of 4-benzamido-1-o-aminoacetophenone-3-thiosemicarbazone complexes. Transition Met Chem 14, 209–212 (1989). https://doi.org/10.1007/BF01043797

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  • DOI: https://doi.org/10.1007/BF01043797

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