Summary
Iron(III) complexes of the general formula Fe(L)nX3·mH2O, where L=benzoxazole(benzox), 2-methylbenzoxazole(2-Mebenzox), 2, 5-dimethylbenzoxazole(2, 5-diMebenzox); n=2, 3, 4, 6; X=Cl, Br, NO3 or ClO4; m=0, 1, 2, 5, have been prepared and studied by chemical analysis, magnetic moments, i.r., electronic, Mössbauer spectra and molar conductivity values.
The oxazoles are Nring bonded and the complexes are hexacoordinate in the solid state with exception of the five-coordinate Fe(2, 5-diMebenzox)2Br3.
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Pinna, R., Ponticelli, G., Aramu, F. et al. Iron(III) complexes with benzoxazole derivatives. Transition Met Chem 13, 426–428 (1988). https://doi.org/10.1007/BF01043703
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DOI: https://doi.org/10.1007/BF01043703