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Synthesis of new maleimide monomers having a perfluoroaliphatic side chain and study of their copolymerization with vinelethers

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Summary

A fluorinated maleimide has been prepared from fluorinated diol with monofluoronitrobenzene. All the intermediates have been perfectly characterized by N.M.R. The study also describes the synthesis of a copolymer from a commercial vinyl ether and this maleimide. Copolymerization is not perfectly alternated as we could expect but the copolymer exhibits a glass transition equal to 165°C.

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Beaune, O., Bessiere, JM., Boutevin, B. et al. Synthesis of new maleimide monomers having a perfluoroaliphatic side chain and study of their copolymerization with vinelethers. Polymer Bulletin 29, 605–612 (1992). https://doi.org/10.1007/BF01041144

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