Summary
A systematic study of the effect of substitution on the thermodynamic stability of the 1∶1 complexes which the UO II2 ion forms in aqueous media with salicylic acid and ten monosubstituted salicylic acids has been carried out using a new spectrophotometric method. The new features of the method as well as a thermodynamic treatment for the effect of substitution is discussed.
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References
M. M. Andrews,J. Biochem.,75, 298 (1960).
W. O. Foye and J. G. Turcotte,J. Pharm. Sci.,51, 329 (1962).
Salicylates: An International Symposium, Sponsored by the Empire Rheumatism Council, Churchill, London, 1963.
K. N. von Kaulla and G. Ens,Biochem. Pharmac.,16, 1023 (1967).
M. S. Tute,Rep. Prog. App. Chem.,55, 570 (1970).
E. Peligot,J. Prakt. Chem.,35, 153 (1945).
H. Itzig,Ber, Chem. Dtsch. Ges.,34, 3822 (1901).
I. Feldman and J. R. Havill,J. Am. Chem. Soc.,76, 2114 (1954).
I. Feldman, J. R. Havill and W. F. Neuman,J. Am. Chem. Soc.,76, 4726 (1954).
S. Hakamori,Chem. Abstr.,26, 2366 (1932).
G. Courtois,Bull. Soc. Chim. Fr.,33, 1761 (1923).
R. T. Foley and R. C. Anderson,J. Am. Chem. Soc.,71, 909 (1949).
C. V. Banks and R. S. Singh,J. Inorg. Nucl. Chem.,15, 125 (1960).
R. S. Rajan and A. E. Martell,J. Inorg. Nucl. Chem.,26, 789 (1964).
D. V. Jahagirdar and D. D. Khanolkar,J. Inorg. Nucl. Chem.,35, 921 (1973).
H. von Halban,J. Proc. Roy. Soc.,A 116, 153 (1927).
A. Ringhorn,Z. Anal. Chem.,115, 332 (1939).
C. W. Davies,Ion Association, Butterworths, London, 1962, p. 41.
H. G. Jerrard and D. B. McNeil,Theoretical and Experimental Physics, Chapman and Hall, London, 1960, p. 13.
Y. Z. Yousif,Ph.D. Thesis, C.N.A.A., (1973).
E. Larsson,Z. Physik. Chem. Leipzig,A 169, 207 (1934).
J. Bjerrum,Chem. Rev.,46, 381 (1950).
A. E. Martell and M. Calvin,Chemistry of the Metal Chelate Compounds, Prentice-Hall, New York, 1952.
D. D. Perrin,J. Chem. Soc., 3125 (1958).
E. R. Tucci, C. H. Ke and N. C. Li,J. Inorg. Nucl. Chem.,29, 1657 (1967).
M. Bartusk,J. Inorg. Nucl. Chem.,29, 1089 (1967).
Y. Z. Yousif and F. J. M. Al-Imarah,J. Inorg. Nucl. Chem.,42, 779 (1980).
H. W. Irving and H. S. Rossotti,Acta Chem. Scand.,10, 72 (1956).
J. G. Jones, J. B. Poole, J. C. Tomkinson and R. J. P. Williams,J. Chem. Soc., 2001, 2010, (1958).
Z. L. Ernst and J. Menashi,Trans. Faraday Soc.,59, 2838 (1963).
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Yousif, Y.Z., Al-Imarah, F.J.M. Spectrophotometric study of the effect of substitution on the thermodynamic stability of the 1∶1 complexes of the dioxouranium(II) ion with mono-substituted salicylic acids in aqueous media. Transition Met Chem 14, 123–126 (1989). https://doi.org/10.1007/BF01040605
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DOI: https://doi.org/10.1007/BF01040605