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Chromatographic determination of polymer solubility parameters

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Summary

Weight fraction activity coefficients (Ω1)∞ and interaction parameters x have been determined for seven different solvents in Polyarylate at three temperatures by the gas chromatographic method (inverse gas chromatography). Data have been used to calculate infinite dilution solubility parameters according to the method proposed by DiPaola-Baranyi and Guillet. The validity of the plots involved in the above mentioned method is also discussed.

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Authors and Affiliations

  1. Departamento de Quimica Fisica y Macromoléculas, Facultad de C. Quimicas, Universidad del Pais Vasco, P.O. Box 1072, San Sebastian, Spain

    J. I. Eguiazabal, M. J. Fernández-Berridi, J. J. Iruin & J. M. Elorza

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  1. J. I. Eguiazabal
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  2. M. J. Fernández-Berridi
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  3. J. J. Iruin
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  4. J. M. Elorza
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Eguiazabal, J.I., Fernández-Berridi, M.J., Iruin, J.J. et al. Chromatographic determination of polymer solubility parameters. Polymer Bulletin 13, 463–467 (1985). https://doi.org/10.1007/BF01033346

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  • DOI: https://doi.org/10.1007/BF01033346

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