Advertisement

Polymer Bulletin

, Volume 26, Issue 5, pp 481–485 | Cite as

Michael addition polymers from bisacetoacetates

II. 2,2-dimethyl-1,3-bis(acetoacetyl)-propanediol andN,N′-bis(acetoacetyl)-1,4-piperazine
  • David L. Trumbo
Article

Summary

The Michael reaction was used to synthesize polymers from bisacetoacetyl esters and amides and a diacrylate. The reaction occurred readily at room temperature yielding semi-solid polymers with broad molecular weight distributions which narrowed as the reaction progressed. The polymers based on the amide had lower molecular weights than those based on the ester.

Keywords

Polymer Ester Molecular Weight Amide Lower Molecular Weight 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    D. L. Trumbo, submitted for publication, Polym. Bull., 1990.Google Scholar
  2. 2.
    J. S. Witzeman, W. D. Nottingham and F. D. Rector, Proceeding of the Sixteenth Waterborne and Higher Solids Coating Symposium, 400 (1989).Google Scholar
  3. 3.
    R. S. Clemens and F. D. Rector, J. of Coat. Technol., 61, 83 (1989).Google Scholar
  4. 4.
    S. J. Huang and P. G. Edelman, Polym. Preprints, Vol. 25, No. 2, 63 (1984).Google Scholar
  5. 5.
    E. D. Bergmen, D. Ginsburg and R. Pappo, Org. Reactions, 10, 179 (1989).Google Scholar
  6. 6.
    P. J. Flory, “Principles of Polymer Chemistry”, Cornell Univ. Press, Ithaca, NY 1953.Google Scholar

Copyright information

© Springer-Verlag 1991

Authors and Affiliations

  • David L. Trumbo
    • 1
  1. 1.The Glidden CompanyStrongsvilleUSA

Personalised recommendations