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Spectroscopic studies of epoxy resin coating on imidazole copolymer treated copper surfaces

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Summary

The reaction between the epoxy resin coating and copper surface modified with imidazole copolymer has been studied by FT-IR reflection-absorption spectroscopy (FT-IR RAS). Due to the catalytic effect of the copper/imidazole complex, epoxy cure reaction has occurred on the copper surface at low temperature. The cured epoxy coating has been increased gradually above 150 °C, while the imidazole complex dissolved slightly into the resin solution. Compared to poly(vinylimidazole) homopolymer, silane-based imidazole copolymer coating remains more on the copper surface due to the adhesion promotion between copper surface and coating polymer.

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Authors and Affiliations

  1. Polymer Composites Laboratory, Korea Institute of Science and Technology, Cheongryang, P.O.Box 131, 131, Seoul, Korea

    Jyongski Jang

  2. Department of Chemical Technology, Seoul National University, Sinlimdong Kwanakgu, 151-742, Seoul, Korea

    Jyong Sup Shim

Authors
  1. Jyongski Jang
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  2. Jyong Sup Shim
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Jang, J., Shim, J.S. Spectroscopic studies of epoxy resin coating on imidazole copolymer treated copper surfaces. Polymer Bulletin 25, 677–682 (1991). https://doi.org/10.1007/BF01032664

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