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Effect of the polymer structure and tacticity on the oxidizing ability of polyvinylpyridinium dichromate

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Summary

Poly (2-vinylpyridinium dichromate) oxidizes different alcohols to their corresponding carbonyl compounds more efficiently than poly (4-vinylpyridinium dichromate). Syndiotactic form of the 2-isomer is the most efficient.

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References and footnotes

  1. Holt P.F, Nassrallah E.T. (1986) J. Chem. Soc. B: 233

  2. Holt P.F., Lindsay H (1969) J. Chem. Soc. B: 54

  3. Holt P.F., Tamami B (1970) Polymer: 553

  4. Holt P.F, Lindsay H, Beck E.G. (1970) Br. J. Pharma. 38: 192

    Google Scholar 

  5. Natta G, Mozzanti G, Longi P, Dall asta G, Bernardini F (1961) J. Polym. Sci. 51: 486, and (1960) Makromol. Chem. 37: 160

    Google Scholar 

  6. Geuskens G, Lubikulu J.C., David C (1966) Polymer 7: 63

    Google Scholar 

  7. Information about the tacticities of the Polymers were obtained by using high resolution nuclear magnetic resonance spectroscopy, a method reported in ref. 6.

  8. Akalah A, Sherington D.C (1981) Chem. Rev. 81: 557

    Google Scholar 

  9. Frechet J.M.J., Meftahi M.Y (1984) Brit. Polym. J. 16: 164

    Google Scholar 

  10. Unpublished results.

  11. Tamami B, Hatam M, Mohadjer D (1989) Polymer Bull. 21: 531

    Google Scholar 

  12. Frechet J.M.J, Darling P, Faral M.J (1981) J. Org. Chem. 46: 1728

    Google Scholar 

  13. Aldrich Cat. No. 23746-9 (1988).

  14. Brandrup J, Immergut E.H (1966) Polymer Handbook, 2nd edn. John Wieley, New York.

    Google Scholar 

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Tamami, B., Goudarzian, N. Effect of the polymer structure and tacticity on the oxidizing ability of polyvinylpyridinium dichromate. Polymer Bulletin 23, 295–298 (1990). https://doi.org/10.1007/BF01032444

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