Transition Metal Chemistry

, Volume 15, Issue 1, pp 51–57 | Cite as

Coordination chemistry of f-block elements with imine acids. Part IV. Synthetic and chiroptical studies on lanthanide(III) complexes of imine acids derived from L-alanine, L-valine, L-tyrosine and L-glutamic acid

  • Rita Roy
  • Manik C. Saha
  • Parag S. Roy
Full Papers

Summary

N-(orthovanillidene)L-alanine (OVAlaH2), N-(salicylidene)L-valine (SValH2), N-(orthovanillidene)L-valine (OVValH2), N-(orthovanillidene)L-tyrosine (OVTyrH3) and N-(salicylidene)L-glutamic acid (SGluH3) react with LaIII, PrIII, NdIII and SmIII to yield new chiral complexes. Their dominant conformers were determined from c.d. spectra supported by1H n.m.r. data, except for the L-glutamic acid derived complexes which were insoluble.

Keywords

Physical Chemistry Inorganic Chemistry Catalysis Coordination Chemistry Salicylidene 

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Copyright information

© Chapman Hall Ltd 1990

Authors and Affiliations

  • Rita Roy
    • 1
  • Manik C. Saha
    • 1
  • Parag S. Roy
    • 1
  1. 1.Department of ChemistryUniversity of North BengalDarjeelingIndia

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