Transition Metal Chemistry

, Volume 15, Issue 1, pp 51–57 | Cite as

Coordination chemistry of f-block elements with imine acids. Part IV. Synthetic and chiroptical studies on lanthanide(III) complexes of imine acids derived from L-alanine, L-valine, L-tyrosine and L-glutamic acid

  • Rita Roy
  • Manik C. Saha
  • Parag S. Roy
Full Papers


N-(orthovanillidene)L-alanine (OVAlaH2), N-(salicylidene)L-valine (SValH2), N-(orthovanillidene)L-valine (OVValH2), N-(orthovanillidene)L-tyrosine (OVTyrH3) and N-(salicylidene)L-glutamic acid (SGluH3) react with LaIII, PrIII, NdIII and SmIII to yield new chiral complexes. Their dominant conformers were determined from c.d. spectra supported by1H n.m.r. data, except for the L-glutamic acid derived complexes which were insoluble.


Physical Chemistry Inorganic Chemistry Catalysis Coordination Chemistry Salicylidene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. (1).
    D. E. Fenton, U. Casellato, P. A. Vigato and M. Vidali,Inorg. Chim. Acta,95, 187 (1984).Google Scholar
  2. (2).
    S. P. Sinha,Structure and Bonding,25, 69 (1975).Google Scholar
  3. (3).
    J. H. ForsebergCoord. Chem. Rev.,10, 195 (1973).Google Scholar
  4. (4).
    J. C. G. Bunzli and D. Wessner,Coord. Chem. Rev.,60 191 (1984).Google Scholar
  5. (5).
    A. Chisari, A. Musumeci, M. Vidali and A. Seminara,Inorg. Chim. Acta,81, L19 (1984).Google Scholar
  6. (6).
    E. Nieboer,Structure and Bonding,22, 1 (1975).Google Scholar
  7. (7).
    D. M. Dooley and J. H. Dawson,Coord. Chem. Rev.,60, 1 (1984).Google Scholar
  8. (8).
    L. F. Lindoy,Coord. Chem. Rev.,48, 83 (1983).Google Scholar
  9. (9).
    R. E. Sievers (Ed.),Nuclear Magnetic Resonance Shift Reagents, Academic Press, New York, 1973.Google Scholar
  10. (10).
    J. A. Glasel,Prog. Inorg. Chem.,18, 383 (1973).Google Scholar
  11. (11).
    R. M. Silverstein, G. C. Bassler and T. C. Morril,Spectrometric Identification of Organic Compounds, Wiley, New York, 1981, p. 213.Google Scholar
  12. (12).
    H. G. Brittain,Coord. Chem. Rev.,48, 243 (1983).Google Scholar
  13. (13).
    F. S. Richardson and J. P. Riehl,Chem. Rev.,77, 773 (1977).Google Scholar
  14. (14).
    F. S. Richardson and T. R. Faulkner,J. Chem. Phys.,76, 1595 (1982).Google Scholar
  15. (15).
    J. J. Calienni and H. G. Brittain,Inorg. Chim. Acta,116, 163 (1986).Google Scholar
  16. (16).
    G. L. Eichhorn,Inorganic Biochemistry, Elsevier Scientific Publishing Co., New York, 1975, Vols. 1 and 2, Ch. 31.Google Scholar
  17. (17).
    M. D. Tsai, S. R. Byrn, C. Chang, H. G. Floss and H. J. R. Weintraub,Biochemistry,17, 3177 (1978).Google Scholar
  18. (18).
    M. J. Makela and T. K. Korpela,Chem. Soc. Rev.,12, 309 (1983).Google Scholar
  19. (19).
    H. E. Smith,Chem. Rev.,83, 359 (1988).Google Scholar
  20. (20).
    J. Frelek, Z. Majer, A. Perkowska, G. Snatzke, I. Vlahov and U. Wagner,Pure & Appl. Chem.,57, 441 (1985).Google Scholar
  21. (21).
    R. Roy, M. C. Saha and P. S. Roy,Inorg. Chim. Acta,129, 265 (1987).Google Scholar
  22. (22).
    S. J. Lyle and MD. M. Rahman,Talanta,10, 1177 (1963).Google Scholar
  23. (23).
    J. Korbl and R. Pribil,Chemist-Analyst,45, 102 (1956).Google Scholar
  24. (24).
    W. J. Geary,Coord. Chem. Rev.,7, 110 (1971).Google Scholar
  25. (25).
    B. N. Figgis,Introduction to Ligand Fields, Wiley Eastern Ltd., 1976.Google Scholar
  26. (26).
    L.Cattalini, S. Degetto, M. Vidali and P. A. Vigato,Inorg. Chim. Acta,6, 173 (1972).Google Scholar
  27. (27).
    A. Seminara, S. Giuffrida, A. Musumeci and I. Fragala,Inorg. Chim. Acta,95, 201 (1984).Google Scholar
  28. (28).
    U. Casellato, P. A. Vigato and M. Vidali,Coord. Chem. Rev.,26, 85 (1978).Google Scholar
  29. (29).
    G. B. Deacon and R. J. Phillips,Coord. Chem. Rev.,33, 227 (1980).Google Scholar
  30. (30).
    H. M. Dawes, J. M. Water and T. N. Waters,Inorg. Chim. Acta,66, 29 (1982).Google Scholar
  31. (31).
    P. C. Kundu and P. S. Roy,J. Inorg. Nucl. Chem.,43, 987 (1981).Google Scholar
  32. (32).
    T. Ueki, T. Ashida, Y. Sasada and M. Kadudo,Acta Cryst.,B25, 328 (1969).Google Scholar
  33. (33).
    R. Hamalainen, U. Turpeinen, M. Ahlgren and M. Rantala,Acta Chem. Scand.,A32, 549 (1978).Google Scholar
  34. (34).
    K. Korhonen, R. Hamalainen and U. Turpeinen,Acta Cryst.,C40, 1175 (1984).Google Scholar
  35. (35).
    F. A. Cotton (Ed.),Prog. Inorg. Chem.,8, 195, 226 (1967).Google Scholar
  36. (36).
    J. R. Ferraro,Low-Frequency Vibrations of Inorganic and Coordination Compounds, Plenum Press, New York, 1971, pp. 78, 80, 98, 104.Google Scholar
  37. (37).
    D. M. Adams,Metal-Ligand and related vibrations, Edward Arnold (Publishers) Ltd., London, 1967, pp. 281, 310.Google Scholar
  38. (38).
    B. C. Baker and D. T. Sawyer,Inorg. Chem.,8, 1160 (1969);Anal. Chem.,40, 1945 (1968).Google Scholar
  39. (39).
    S. Castellano, H. Gunther and S. Ebersole,J. Phys. Chem.,69, 4166 (1965).Google Scholar
  40. (40).
    J. D. Miller and R. H. Prince,J. Chem. Soc., 4706 (1965).Google Scholar
  41. (41).
    M. C. Saha, R. Roy and P. S. Roy, Unpublished results.Google Scholar
  42. (42).
    T. Moeller,Comprehensive Inorganic Chemistry, J. C. Bailer, Jr., H. J. Emeleus, R. Nyholm and A. F. Trotman-Dickenson (Ed.), Pergamon Press, Oxford, 1973, Vol. 4, p. 1.Google Scholar
  43. (43).
    J. C. Barns,J. Chem. Soc., 3880 (1964).Google Scholar
  44. (44).
    A. Pasini, M. Gullotti and E. Cesarotti,J. Inorg. Nucl. Chem.,34, 3821 (1972).Google Scholar
  45. (45).
    H. E. Smith and F. M. Chen,J. Org. Chem.,46, 185 (1981).Google Scholar

Copyright information

© Chapman Hall Ltd 1990

Authors and Affiliations

  • Rita Roy
    • 1
  • Manik C. Saha
    • 1
  • Parag S. Roy
    • 1
  1. 1.Department of ChemistryUniversity of North BengalDarjeelingIndia

Personalised recommendations