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Chemistry of Heterocyclic Compounds

, Volume 5, Issue 1, pp 1–3 | Cite as

Investigations in the field of oxygen-containing heterocycles

VIII. The addition of 2,3-dichlorotetrahydrofuran to dienes
  • Yu. I. Tarnopol'skii
  • A. K. Nadelyaeva
Article

Abstract

In the presence of stannic chloride, 2,3-dichlorotetrahydrofuran adds to isoprene with the formation of 3-chloro-2-(4′-chloro-2′-methylbut-2′-enyl)tetrahydrofuran and to piperylene and bivinyl with the formation, predominantly, of 3-chloro-2-(4′-chloropent-2′-enyl)- and 3-chloro-2′-(4′-chlorobut-2′-enyl)tetrahydrofuran, respectively, with their allyl isomers. The amount of the latter was estimated from the NMR spectra at 20–30%.

Keywords

Chloride Organic Chemistry Allyl Tetrahydrofuran Isoprene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

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Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • Yu. I. Tarnopol'skii
    • 1
  • A. K. Nadelyaeva
    • 1
  1. 1.Siberian Technological InstituteKrasnoyarsk

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