Advertisement

The structure of the mineralomimetic cadmium cyanide-dimethyl carbonate clathrate

  • Takafumi Kitazawa
Article

Abstract

Cd(CN)2·(CH3O)2CO (1) contains a mineralomimetic framework of Cd(CN)2 analogous to the low temperature form of cristobalite. The host framework is isostructural to those of previously reported Cd(CN)2·G compounds (G = CHCl2CH2Cl2, (CH3)2CHBr3). The dimethyl carbonate molecules in the adamantane-like cage display orientation disorder associated with the location of the carbonyl oxygen atom.

Key words

Cadmium cyanide crystal structure clathrate mineralomimetic chemistry dimethyl carbonate 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    T. Kitazawa and M. Takeda:J. Chem. Soc., Chem. Commun. 309 (1993).Google Scholar
  2. 2.
    T. Kitazawa, M. Akiyama, M. Takahashi and M. Takeda:J. Chem. Soc., Chem. Commun. 1112 (1993).Google Scholar
  3. 3.
    T. Kitazawa. T. Kikuyama, M. Takahashi and M. Takeda:J. Chem. Soc., Dalton Trans. 2933 (1994).Google Scholar
  4. 4.
    T. Kitazawa, S. Nishikiori, R. Kuroda and T. Iwamoto:Chem. Lett. 459 (1988).Google Scholar
  5. 5.
    T. Kitazawa, S. Nishikiori, R. Kuroda and T. Iwamoto:Chem. Lett. 1729 (1988).Google Scholar
  6. 6.
    T. Kitazawa, T. Kikuyama, M. Takeda and T. Iwamoto:J. Chem. Soc., Dalton Trans. 3715 (1995).Google Scholar
  7. 7.
    T. Kitazawa, S. Mishikiori and T. Iwamoto:J. Chem. Soc., Dalton Trans. 3695 (1994).Google Scholar
  8. 8.
    T. Kitazawa, S. Nishikiori, R. Kuroda and T. Iwamoto:J. Chem. Soc. Dalton Trans. 1029 (1994).Google Scholar
  9. 9. (a)
    T. Iwamoto, inInclusion Compounds, J.L. Atwood, J.E.D. Davies and D.D. MacNicol (eds.), Oxford University Press, Oxford, 1991, vol. 5, pp. 172–212.Google Scholar
  10. 9. (b)
    T. Iwamoto, T. Kitazawa, S. Nishikiori and R. Kuroda, inChemical Physics of Intercalation II, NATO ASI series B, vol. 305, P. Bernier, J. E. Fischer, S. Roth and S. A. Solin (eds.), Plenum, New York, 1993, pp. 325–332.Google Scholar
  11. 9. (c)
    T. Iwamoto, S. Nishikiori and T. Kitazawa,Supramol. Chem. 6, 179, (1995).Google Scholar
  12. 10.
    T. Kitazawa, S. Nishikiori and T. Iwamoto:Mater Sci. Forum 91–93, 257 (1992).Google Scholar
  13. 11.
    T. Kitazawa, H. Sugisawa, M. Takeda and T. Iwamoto:J. Chem. Soc., Chem. Commun. 233 (1993).Google Scholar
  14. 12. (a)
    B.F. Abrahams, B.F. Hoskins and R. Robson:J. Chem. Soc., Chem. Commun. 60 (1990).Google Scholar
  15. 12. (b)
    B.F. Hoskins and R. Robson:J. Am. Chem. Soc. 112, 1546 (1990).Google Scholar
  16. 12. (c)
    B. F. Abrahams, B. F. Hoskins, J. Liu and R. Robson:J. Am. Chem. Soc. 113, 3045 (1991).Google Scholar
  17. 12. (d)
    B. F. Abrahams, M. J. Hardie, B. F. Hoskins, R. Robson and G. A. Williams:J. Am. Chem. Soc. 114, 10641 (1992).Google Scholar
  18. 13.
    S. Nishikiori, C. I. Ratcliffe and J. A. Ripmeester:J. Am. Chem. Soc. 114, 8590 (1992).Google Scholar
  19. 14.
    J. Kim, D. Whang, J. I. Lee and K. Kim:J. Chem. Soc., Chem. Commun. 1400 (1993).Google Scholar
  20. 15.
    E. Ruiz and S. Alvarez:Inorg. Chem. 34, 5845 (1995).Google Scholar
  21. 16.
    H. Arnord:International Tables for Crystallography, T. Hahn (ed.), Kluwer Academic Publishers, Dordrecht, 1989, vol. A, Section 5.5., pp. 74–75.Google Scholar
  22. 17.
    TEXSAN Structure Analysis, Molecular Structure Corporation, Texas, 1987.Google Scholar
  23. 18.
    G.M. Sheldrick:shelxl-93.Program for the Refinement of Crystal Structures, Univ. of Gottingen, Germany, 1993.Google Scholar
  24. 19.
    C. K. Johnson: ORTEP II, REPORT ORNL-5138, Oak Ridge National Laboratory, Tennessee, (1976).Google Scholar
  25. 20.
    S. Nishikiori, C. I. Ratcliffe, and J. A. Ripmeester:J. Phys. Chem. 94, 8098 (1990).Google Scholar

Copyright information

© Kluwer Academic Publishers 1996

Authors and Affiliations

  • Takafumi Kitazawa
    • 1
  1. 1.Department of Chemistry, Faculty of ScienceToho UniversityChibaJapan

Personalised recommendations