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A test of the onsager reciprocal relations and a discussion of the ionic isothermal vector transport coefficientsI Ij for aqueous AgNO3 at 25°C

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Abstract

Values ofI ij calculated from experimental data are given for AgNO3 at 25°C. Experimental values of the ratioI 12/I21 are calculated to provide a sensitive direct test of the Onsager reciprocal relations,I 12=I21. This ratio is found to be unity within experimental error (ca. 2%). The general physical interpretation ofI ij/N as mobilities is discussed. An approximate way of estimatingI ij for dissociated salts is considered. A comparison is made between AgNO3 I ij data and corresponding data for NaCl and KCl. It is concluded that ion-pair formation (1) sharply increases the magnitude of the interaction mobility,I 12/N; and (2) increases the “intrinsic mobility” of Ag+,I 11/N, and decreases the intrinsic mobility of NO −3 ,I 22/N.

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Authors and Affiliations

  1. Lawrence Livermore Laboratory, University of California, Livermore, California

    Donald G. Miller

  2. Chemistry Department, University of Tennessee, Knoxville, Tennessee

    Michael J. Pikal

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  1. Donald G. Miller
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  2. Michael J. Pikal
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Miller, D.G., Pikal, M.J. A test of the onsager reciprocal relations and a discussion of the ionic isothermal vector transport coefficientsI Ij for aqueous AgNO3 at 25°C. J Solution Chem 1, 111–130 (1972). https://doi.org/10.1007/BF01028449

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  • DOI: https://doi.org/10.1007/BF01028449

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