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Transition Metal Chemistry

, Volume 16, Issue 5, pp 535–541 | Cite as

Solvent effects upon reactions between ions: hexacyanoferrate(II)-peroxodisulphate and sulphite-hexacyanoferate(III)

  • Amalia Rodríguez
  • Carmen Carmona
  • Ernestina Muñoz
  • Francisco Sánchez
  • John Burgess
Full Papers

Summary

Different approaches to the interpretation of solvent effects on reactions between ionic reactants are analysed, taking as a basis the kinetic data corresponding to the sulphite-hexacyanoferrate(III) and peroxodisulphate-hexacyanoferrate(III) oxidations. It is concluded that the approach based on the use of solvent parameters is the more promising, although knowledge of the transfer chemical potentials of the reactants may also be useful in the interpretation of kinetic behaviour.

Keywords

Oxidation Physical Chemistry Inorganic Chemistry Catalysis Kinetic Data 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman & Hall 1991

Authors and Affiliations

  • Amalia Rodríguez
    • 1
  • Carmen Carmona
    • 1
  • Ernestina Muñoz
    • 1
  • Francisco Sánchez
    • 1
  • John Burgess
    • 2
  1. 1.Departmento de Química FisicaUniversidad de SevillaSevillaSpain
  2. 2.Department of ChemistryUniversity of LeicesterLeicesterUK

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