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Novel mixed-ligand derivatives ofbis(acetylacetonato)-bis(methylacetoacetato) andbis(ethylacetoacetate)-nickel(II) with some potentially mono-, bi- and tri-dentate 2/3-pyrazoline-5-ones

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Summary

Novel mixed-ligand nickel(II) complexes having octahedral stereochemistry and general formula [Ni-(acac)2(L)2]/[Ni(meacac)2(L)2]/[Ni(etacac)2(L)2] (where L=3-methyl-1-phenyl-2-pyrazoline-5-one, 2,3-dimethyl-4-methylaminomethanesulphonate sodium monohydrate-1-phenyl-3-pyrazoline-5-one or 4-amino-2,3-dimethyl-1-phenyl-3-pyrazoline-5-one) have been isolated by reacting [Ni(acac)2(H2O)2]/[Ni(meacac)2(H2O)2]/ [Ni(etacac)2(H2O)2] with L in alcohol. The derivatives have been characterized by analytical data, molar conductances, magnetic measurements, electronic and i.r. spectra.

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Authors and Affiliations

  1. Coordination chemistry laboratory, Department of P. G. Studies and Research in Chemistry, R. D. University, 482001, Jabalpur, India

    Ram C. Maurya, Deen D. Mishra, Sudipta Mukherjee & Pramod K. Trivedi

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  1. Ram C. Maurya
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  2. Deen D. Mishra
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  3. Sudipta Mukherjee
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  4. Pramod K. Trivedi
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Maurya, R.C., Mishra, D.D., Mukherjee, S. et al. Novel mixed-ligand derivatives ofbis(acetylacetonato)-bis(methylacetoacetato) andbis(ethylacetoacetate)-nickel(II) with some potentially mono-, bi- and tri-dentate 2/3-pyrazoline-5-ones. Transition Met Chem 16, 524–527 (1991). https://doi.org/10.1007/BF01024323

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  • DOI: https://doi.org/10.1007/BF01024323

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