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Transition metal complexes derived from ethyl-α-(N-phenylthiocarbamyl)cyanoacetate

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Summary

Complexes of CoII, NiII, CuII, ZnII, PdII, CdII, HgII and CuI with ethyl-α-(N-phenylthiocarbamyl)cyanoacetate (HETCA) have been synthesized and characterized. The i.r. spectra show that HETCA behaves as a mononegative bidentate ligand, in the thiol tautomeric form. HETCA reduces CuCl2 to give a diamagnetic CuI complex. A tetrahedral structure is proposed for the CoII complex, while a square-planar structure is proposed for the NiII, CuII, and PdII complexes.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt

    Rafat M. El-Shazly, Magdy M. Bekheit & Gaber M. Abu El-Reash

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  1. Rafat M. El-Shazly
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  2. Magdy M. Bekheit
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  3. Gaber M. Abu El-Reash
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El-Shazly, R.M., Bekheit, M.M. & Abu El-Reash, G.M. Transition metal complexes derived from ethyl-α-(N-phenylthiocarbamyl)cyanoacetate. Transition Met Chem 16, 492–494 (1991). https://doi.org/10.1007/BF01024314

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  • DOI: https://doi.org/10.1007/BF01024314

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