Summary
The interaction of aquo-ethylenediaminetetraacetatoruthenate(III) with ferricyanide ion was studied spectrophotometrically as a function of ferricyanide ion concentration, pH (1.5–8.5) and temperature (30–45°C) at ionic strength 0.2 M (NaClO4). Kinetic and activation parameters (ΔH≠=27.1±1.75 KJ mol−1, ΔS≠=−136.7±5.57 J mol−1 deg−1) are consistent with the proposed mechanism.
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Chatterjee, D., Ghosh, A.K. Kinetics of the interaction of aquo-ethylenediaminetetraacetatoruthenate(III) with ferricyanide ion in water. Transition Met Chem 16, 481–483 (1991). https://doi.org/10.1007/BF01024311
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DOI: https://doi.org/10.1007/BF01024311