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Interaction of palladium(II) with DL-selenamethionine in acidic aqueous solution

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Summary

The interaction of PdII with DL-selenamethionine (SeMet) in acidic aqueous solution was investigated. SeMet was found to act as a bidentate ligand, forming a stable complex with PdII. Binding of the metal ion to the selenoether group creates a new chiral centre, which generates two sets of1H and13C n.m.r. methyl resonances for the two diastereoisomers. The2J values for (77Se−Me) decreased upon complex formation.

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  1. Department of Chemistry, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia

    Anvarhusein A. Isab & Abdul Rahman A. Al-Arfaj

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  1. Anvarhusein A. Isab
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  2. Abdul Rahman A. Al-Arfaj
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Isab, A.A., Al-Arfaj, A.R.A. Interaction of palladium(II) with DL-selenamethionine in acidic aqueous solution. Transition Met Chem 16, 304–307 (1991). https://doi.org/10.1007/BF01024068

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  • DOI: https://doi.org/10.1007/BF01024068

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