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Transition Metal Chemistry

, Volume 16, Issue 3, pp 304–307 | Cite as

Interaction of palladium(II) with DL-selenamethionine in acidic aqueous solution

  • Anvarhusein A. Isab
  • Abdul Rahman A. Al-Arfaj
Full Papers

Summary

The interaction of PdII with DL-selenamethionine (SeMet) in acidic aqueous solution was investigated. SeMet was found to act as a bidentate ligand, forming a stable complex with PdII. Binding of the metal ion to the selenoether group creates a new chiral centre, which generates two sets of1H and13C n.m.r. methyl resonances for the two diastereoisomers. The2J values for (77Se−Me) decreased upon complex formation.

Keywords

Methyl Physical Chemistry Aqueous Solution Inorganic Chemistry Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman and Hall Ltd 1991

Authors and Affiliations

  • Anvarhusein A. Isab
    • 1
  • Abdul Rahman A. Al-Arfaj
    • 1
  1. 1.Department of ChemistryKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia

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