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Palladium(II) and platinum(II) chloride and bromide complexes with some 2-methylpyridyl- or methylquinolyl-benzimidazole, benzoxazole, or benzthiazole

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Summary

Palladium(II) and platinum(II) complexes [MLX2], where L=2-(4′-methyl-2′-pyridyl)benzimidazole (mpbi), 2-(4′-methyl-2′-pyridyl)benzoxazole (mpbo), 2-(4′-methyl-2′-quinolyl)benzoxazole (mpbo), 2-(4′-methyl-8′-quinolyl)benzoxazole (mq'bo), X=Cl. Br, together with M(mqbo)2Br2 and Pt2(mpbt)Cl4, where mpbt=2-(4′-methyl-2′-pyridyl)benzthiazole, have been synthesized and characterized by conductivity and magnetic measurements as well as by i.r. and electronic spectra. The ligands are bidentate chelates through the pyridine or quinoline and isoxazole or imidazole nitrogen atoms. The [MLX2] derivatives arecis, square planar.

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Authors and Affiliations

  1. Istituto di Chimica Generale, Inorganica ed Analitica, Università di Cagliari, Via Ospedale 72, 09124, Cagliari, Italy

    Giovanni Coni, Marcella Massacesi, Gustavo Ponticelli, Giovanna Puggioni & Costantino Putzolu

Authors
  1. Giovanni Coni
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  2. Marcella Massacesi
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  3. Gustavo Ponticelli
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  4. Giovanna Puggioni
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  5. Costantino Putzolu
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Coni, G., Massacesi, M., Ponticelli, G. et al. Palladium(II) and platinum(II) chloride and bromide complexes with some 2-methylpyridyl- or methylquinolyl-benzimidazole, benzoxazole, or benzthiazole. Transition Met Chem 12, 379–381 (1987). https://doi.org/10.1007/BF01024039

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  • DOI: https://doi.org/10.1007/BF01024039

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