Transition Metal Chemistry

, Volume 12, Issue 4, pp 330–331 | Cite as

Reactions of cobalt resacetophenone oximate with heterocyclic nitrogen bases

  • Deepawati R. Nepali
  • Arvind T. Rane
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Summary

Adduct formation constants of the pyridine adducts of the cobalt(II) chelate of resacetophenone oxime in cyclohexanone have been determined spectrophotometrically. Spectral changes in the absorbance were observed in visible range. The stability of the cobalt adducts increases in the following order of the bases: pyridine<4-picoline<3,5-lutidine<1,10-phenanthroline<2,9-neocuproin<2,2′-bipyridyl.

Keywords

Nitrogen Cobalt Catalysis Pyridine Adduct 

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Copyright information

© Chapman and Hall Ltd 1987

Authors and Affiliations

  • Deepawati R. Nepali
    • 1
  • Arvind T. Rane
    • 1
  1. 1.Tata Institute of Fundamental ResearchBombayIndia

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