Summary
The reaction of [Mo(CO)6] with NOHSO4 gives new [Mo(NO)2(CO)2(HSO4)2], [Mo(NO)3(HSO4)3] and [Mo(NO)4(HSO4)2] (HSO4)2 polynitrosyl molybdenum complexes. The structure of none of the complexes was fully determined. The last is probably a hyponitritonitrosyl complex. [Mo(NO)3(HSO4)3] and [Mo(NO)4(HSO4)2] (HSO4)2 with EtAlCl2 form heterogeneous catalytic systems for olefin metathesis.
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Keller, A. Synthesis and properties of polynitrosyl molybdenum complexes. Transition Met Chem 12, 320–323 (1987). https://doi.org/10.1007/BF01024022
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DOI: https://doi.org/10.1007/BF01024022