Summary
Complexes of thiophene-2-carboxaldehyde thiosemicarbazone with RuIII, RhIII, IrIII and PtIV have been prepared and characterized by elemental analyses, molar conductance, room temperature, magnetic moments, infrared and electronic spectral studies. Probable structures for the complexes are suggested. All are diamagnetic except the RuIII complexes and possess octahedral structures. The crystal field parameters of the complexes have also been calculated.
Similar content being viewed by others
References
N. N. Orlova, V. A. Aksenova, D. A. Selidovkin, N. S. Bagdanova and G. N. Pershin,Russ. Pharm. Toxicol., 348 (1968).
K. Butler,US Patent No. 3,382, 266 (1968).
D. J. Bauer, L. St. Vincent, C. H. Kempe and A. W. Downe,Lancet,20, 494 (1963).
H. G. Petering, H. H. Buskik and G. E. Underwood,Cancer Res.,64, 367 (1964).
C. W. Johnson, J. W. Jolyner and R. P. Perry,Antibiotics and Chemotherapy,2, 636 (1952).
B. G. Benns, B. A. Gingers and C. H. Bayley,Appl. Microbiol.,8, 353 (1961).
M. A. Ali, S. E. Livingstone,Coord. Chem. Rev.,13, 101 (1974) and refs. therein.
K. Mukkanti, K. B. Pandeya and R. P. Singh,Ind. J. Chem.,21A, 641 (1982).
S. P. Ghosh, P. Bhattacharjee, L. Dubey and L. K. Mishra,J. Ind. Chem. Soc.,54, 230 (1977).
C. G. Kralinger, J. K. Ridder and J. Reedijk,Transition Met. Chem.,5, 73 (1980).
S. P. Ghosh and A. K. Banerjee,Ind. J. Chem.,2, 312 (1984).
B. N. Figgis and J. Lewis in J. Lewis and R. G. Wilkins (Eds),Modern Coordination Chemistry, Interscience Publishers Inc., New York, 1960.
M. M. Jones,Elementary Coordination Chemistry, Prentice Hall, Englewood Cliffs, N. J., p. 254, 1964.
S. E. Livingstone, J. H. Mayfield, D. S. Moore,Aust. J. Chem.,28, 2531 (1975).
K. W. Fung and K. E. Johnson,Inorg. Chem.,10, 1347 (1971).
C. K. Jorgensen,J. Inorg. Nucl. Chem.,24, 1571 (1962).
S. K. Sengupta, S. K. Sahni and R. N. Kapoor,Ind. J. Chem.,19A, 810 (1980).
A. P. B. Lever,Inorganic Electronic Spectroscopy, Elsevier, New York, 1968.
C. J. Ballhausen, in A. E. Martel (Ed.)Coordination Chemistry, Vol. I, Van Nostrand Reinhold, New York, 1971.
S. N. Poddar and N. Saha,J. Ind. Chem. Soc.,52, 57 (1975).
D. M. Wiles, B. A. Gingras and T. Suprunchuk,Can. J. Chem.,45, 469 (1967).
D. M. Wiles and T. Suprunchuk,Can. J. Chem.,47, 1087 (1969).
K. Mukkanti, K. B. Pandeya and R. P. Singh,Synth. React. Inorg. Met-Org. Chem.,15, 613 (1985).
M. Mashina,Bull. Chem. Soc. Jpn.,37, 974 (1964).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mukkanti, K., Singh, R.P. Complexes of platinum, rhodium, iridium and ruthenium with a thiosemicarbazone derived from thiophene-2-carboxaldehyde. Transition Met Chem 12, 299–301 (1987). https://doi.org/10.1007/BF01024017
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01024017