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Transition Metal Chemistry

, Volume 12, Issue 6, pp 539–543 | Cite as

Mössbauer and other spectral studies of iron(II) complexes with amide-containing ligands

  • Dayakar Gade
  • Balaswamy Gubba
  • Ravindar Vadde
  • Lingaiah Puri
Full Papers

Summary

Iron(II) complexes of the type [FeL2X2] (L=bidentate ligand, X=H2O, Cl, or SCN) and [FeL2] (L=tridentate ligand) with polydentate ligands derived from 2-(acetylamino)benzoic acid, 2-(benzoylamino)benzoic acid,2-[2-aminobenzoylamino]benzoic acid, 2-[amino-carbonyl]benzoic acid, 2-[(phenylamino)carbonyl]-benzoic acid, 2-[aminobenzoyl]benzoic acid and 2-aminobenzanilide have been synthesized and characterized by elemental analyses, conductivity, magnetic susceptibility and i.r., electronic, n.m.r., and Mossbauer spectral studies. The different modes of ligand chelation and the stereochemistry around the metal ion are discussed. The small range of isomer shift values for iron(II) complexes confirms the similar geometry for all the complexes.

Keywords

Iron Inorganic Chemistry Catalysis Carbonyl Magnetic Susceptibility 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman and Hall Ltd 1987

Authors and Affiliations

  • Dayakar Gade
    • 1
  • Balaswamy Gubba
    • 1
  • Ravindar Vadde
    • 1
  • Lingaiah Puri
    • 1
  1. 1.Department of ChemistryKakatiya UniversityWarangalIndia

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