Summary
The mass-spectrometry method has been applied to a study of the interaction of [acacRh(CO)2]+ with aromatic nitro compounds in the gas phase and the reactivity order of these compounds has been determined. The coordination mechanism has been found to depend upon the nature of the nitro compound and its ability to replace carbonyl ligands increases with increasing electron-donor ability of substituents. Specific reactions leading to dissociation of C−H, N−O, and O−H bonds are discussed.
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Zagorevskii, D.V., Nekrasov, Y.S. & Bulatov, A.V. Interaction of [acacRh(CO) n ]+ ions (n=0–2) with aromatic nitro compounds in the gas phase. Transition Met Chem 12, 265–267 (1987). https://doi.org/10.1007/BF01023545
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DOI: https://doi.org/10.1007/BF01023545