Summary
[CrCl3(thf)3] (thf=tetrahydrofuran) reacts with semicarbazones and thiosemicarbazones to yield adducts of the type, [CrCl3L] and [CrCl3L2] (where L=semicarbazones or thiosemicarbazones of furfuraldehyde and indole-3-carboxaldehyde).
I.r. data suggest that L bind via the azomethine nitrogen and oxygen/sulphur. Magnetic studies and lig-and field parameters suggest a tetragonal structure for these complexes.
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Garg, A., Tandon, J.P. Coordination compounds of chromium(III) with semicarbazones and thiosemicarbazones of heterocyclic aldehydes. Transition Met Chem 12, 212–214 (1987). https://doi.org/10.1007/BF01023532
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DOI: https://doi.org/10.1007/BF01023532