Skip to main content
SpringerLink
Log in

Pentafluorothiophenolate derivatives of cobalt(II) and nickel(II). The molecular structure of [Ni(SC6F5)2Ph2PCH2CH2PPh2]

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

The tetrahedral compounds [Co(SC6F5)2L] (L=Ph2P(CH2) n PPh2,n=1, 2 and 3) and the squareplanar compound [Ni(SC6F5)2(PhPCH2CH2PPh2)] have been obtained by mathematical reactions of [MX2L] (M=Co or Ni, X=Cl or Br) and Pb(SC6F5)2. The reaction of pentacoordinate [CoCl(Ph2PCH2CH2PPh2)2]+ and the lead salt yields [CoCl2L] and [Co(SC6F5)2L]. Magnetic moments, u.v. data (both in solution and solid state) and the crystal and molecular structure of the nickel compound are reported.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. G. Dance,Inorg. Chem.,20, 1487 (1981).

    Google Scholar 

  2. K. S. Hagen, D. W. Stephan and R. H. Holm,Inorg. Chem.,21, 2928 (1982).

    Google Scholar 

  3. D. Coucouvanis, M. Kanatzidis, E. Simbon and N. C. Baenzinger,J. Am. Chem. Soc.,104, 1874 (1982).

    Google Scholar 

  4. J. M. Downes, J. Whelan and B. Bosnich,Inorg. Chem.,20, 1081 (1981).

    Google Scholar 

  5. T. E. Wolff, J. M. Berg and R. H. Holm,Inorg. Chem.,20, 174 (1981).

    Google Scholar 

  6. K. S. Hagen and R. H. Holm,Inorg. Chem.,23, 418 (1984).

    Google Scholar 

  7. D. Cruz-Garritz, J. Leal, R. L. Richards and H. Torrens,Transition Met. Chem.,8, 127 (1983).

    Google Scholar 

  8. M. H. B. Stiddard and R. E. Townsend,J. Chem. Soc. (A). 2719 (1970).

  9. R. Salcedo and H. Torrens,Transition Met. Chem.,5, 247 (1980).

    Google Scholar 

  10. W. Beck, K. H. Stetter, S. Tadros and K. E. Schwarzhands,Chem. Ber.,100, 3944 (1967).

    Google Scholar 

  11. W. Beck, W. P. Fehlhammer, K. H. Stetter and S. Tadros,Chem. Ber.,100, 3955 (1967).

    Google Scholar 

  12. G. Bor and G. Natile,J. Organometal. Chem.,26, C33 (197).

    Google Scholar 

  13. W. Beck and K. Stetter,Inorg. Nucl. Chem. Lett., 383 (1966).

  14. K. K. Chow and C. A. McAuliffe,Inorg. Chim. Acta,14, 121 (1975).

    Google Scholar 

  15. W. D. Horrocks, G. R. VanHecke and D. W. Hall,Inorg. Chem.,6, 694 (1967).

    Google Scholar 

  16. G. Booth and J. Chatt,J. Chem. Soc(A), 3238 (1965).

  17. M. E. Peach,Can. J. Chem.,46, 2699 (1968).

    Google Scholar 

  18. P. Main, S. J. Fiske, S. E. Hull, L. Lessinger, G. Germain, J. P. Declercq and M. M. WoolfsonMULTAN80, A system of Computer Programs for the Automatic Solution of Crystal Structures from X-ray Diffraction Data, Univ. York (England) and Louvain (Belgium), 1980.

    Google Scholar 

  19. G. M. Sheldrick,A Program or Crystal Structure Determination, Univ. of Cambridge (England), 1976.

    Google Scholar 

  20. J. C. Cloyd and D. W. Meek,Inorg. Chim. Acta,6, 480 (1972).

    Google Scholar 

  21. K. K. Chow and C. A. McAuliffe,Inorg. Chem.,14, 5 (1975).

    Google Scholar 

  22. J. K. Stalick P. W. P. Corfield and D. W. Meek,Inorg. Chem.,12, 1668 (1973).

    Google Scholar 

  23. Q. B. Bao, S. J. Landon, A. L. Rheingold, T. B. Brill and T. M. Haller,Inorg. Chem.,24, 900 (1985).

    Google Scholar 

  24. V. W. Beck and S. Tadros,Z. Anorg. Allq. Chem.,375, 231 (1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. División de Estudios de Posgrado, Facultad de Química, UNAM, 04510, México, D.F., México

    R. M. Catalá, M. E. Colsa, D. Cruz-Garritz & H. Torrens

  2. Departmento de Cristalografía, Universidad Autónoma de Barcelona, Bellaterra (Barcelona), Spain

    J. L. Brianso & J. E. Piniella

  3. Unité de Chimie Physique Moléculaire et de Cristallographie, Université de Louvain, 1 Place Louis Pasteur, Louvain-La-Neuve, Belgium

    G. Germain

Authors
  1. R. M. Catalá
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. E. Colsa
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. Cruz-Garritz
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. Torrens
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. L. Brianso
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. J. E. Piniella
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. G. Germain
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Catalá, R.M., Colsa, M.E., Cruz-Garritz, D. et al. Pentafluorothiophenolate derivatives of cobalt(II) and nickel(II). The molecular structure of [Ni(SC6F5)2Ph2PCH2CH2PPh2]. Transition Met Chem 12, 197–199 (1987). https://doi.org/10.1007/BF01023527

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01023527

Keywords

Search

Navigation