Abstract
The electrolytic treatment of less resistant metals such as iron, copper and nickel with tantalum or niobium has been carried out in K2TaF7-LiF-NaF or K2NbF7-LiF-NaF solutions in the 550 to 1050°C temperature range. Two kinds of experiments have been used.
-
(i)
At lower temperatures, electroplating with pure tantalum and niobium on inert cathodes was performed. The electrodeposition mechanism of each metal was studied and coherent electroplates were prepared which were tested in electrocatalytic applications.
-
(ii)
At higher temperatures (850–1050°C), using nickel cathodes, intermetallic compounds were obtained at more positive potentials than that for pure electrodeposition (Ta2Ni, TaNi, TaNi2, TaNi3, NbNi, NbNi3). The electrowinning of stable TaNi3 and NbNi3 layers was carried out by the metalliding process which makes these materials resistant to corrosion in various media. Further, a study of the kinetics of growth of the diffusion layer allowed a diffusion parameter to be determined which was in agreement with other results obtained by conventional methods.
Similar content being viewed by others
References
R. S. Sethi,J. Appl. Electrochem. 9 (1979) 411.
N. C. Cook,Sci. American 221 (1969) 38.
G. N. Trusov, E. P. Gochalieva, B. A. Goncharenko and V. S. Mikhaeev,Electrokhimiya 13 (1977) 7, 1056.
T. Fujii and H. Baba,Boshoku Gijutsu 29 (1980) 9, 457.
Idem T. Fujii and H. Baba, Jpn Kokai Tokyo Koh 7947 812, 14 April 1979.
P. Taxil and J. Mahenc,Corr. Sci. 21 (1981) 31.
P. Taxil,J. Less Common Metals 113 (1985) 89.
G. W. Mellors and S. Senderoff,J. Electrochem. Soc. 112 (1965) 266.
M. Hansen and K. Anderko, ‘Constitution of Binary Alloys’, McGraw Hill, New York (1958).
U. Cohen, PhD Dissertation, Standord, USA (1977).
P. Taxil and Z. Y. Qiao,J. Chim. Phys. 82 (1985) 83.
Z. Y. Qiao and P. Taxil,J. Appl. Electrochem. 15 (1985) 259.
P. Taxil, Thesis, Toulouse (1986).
A. Brenner, ‘Electrodeposition of Alloys’, Vol. 1, Academic Press, New York (1963).
S. N. Nesterenko, L. L. Meshkov and C. M. Sokolovskaya,Vest. Mosk. Univ. Ser. 2 Khim. 22 (1981) 305.
N. P. Lyakishev, Yu. P. Snitko and V. I. Alekseiev,Dokl. Akad. Nauk. SSSR 258 (1981) 1404.
P. Taxil and Z. Y. Qiao,J. Appl. Electrochem. 15 (1985) 947.
J. Crank, ‘The Mathematics of the Diffusion’, Oxford University Press, London (1964).
W. Jost, ‘Diffusion in Solids, Liquids, Gases’, Academic Press, New York (1960).
P. V. Danckwerts,Trans. Faraday Soc. 46 (1950) 701.
U. Cohen,J. Electrochem. Soc. 128 (1981) 731.
N. Ibl, J. C. Puippe and H. Angerer,Surf. Technol. 6 (1978) 287.
G. Lodi, F. Silvieri, A. De Battesti and S. Trasatti,J. Appl. Electrochem. 8 (1978) 135.
R. Kotz, H. J. Lewerenz and S. Stucki,J. Electrochem. Soc. 130 (1983) 825.
Y. Muramatsu,Trans. Nat. Res. Inst. Met. 17 (1975) 21.
M. P. Arbusov and V. G. Chuprina,Poroshk Metall. (Kiev) (1978)2, 72.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Taxil, P., Mahenc, J. Formation of corrosion-resistant layers by electrodeposition of refractory metals or by alloy electrowinning in molten fluorides. J Appl Electrochem 17, 261–269 (1987). https://doi.org/10.1007/BF01023292
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01023292