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Transition Metal Chemistry

, Volume 12, Issue 1, pp 58–62 | Cite as

Mixed-ligand complex-formation of (2,2′,2″-terpyridine) copper(II) with monosubstituted phenolates

  • Whei-Lu Kwik
  • Kok-Peng Ang
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Summary

The copper(II)-phenolate oxygen interaction in several mixed-ligand complexes of copper(II) containing a 2,2′,2″-terpyridyl and a phenolate has been studied by i.r., electronic, e.p.r. spectroscopies and conductometric and polarographic measurements. Electronic spectral results demonstrate the dependence of such interaction on the nature of the phenol as well as the solvent. Partial dissociation of the phenolate from the complex was detected in methanol at low concentrations (≤1×10−4M). In dimethyl sulphoxide the complexes remain intact. The X-band e.p.r. spectral data obtained at ambient temperature and at 77 K are consistent with the results from the electronic spectral and conductometric study.

Keywords

Copper Phenolate Catalysis Ambient Temperature Dimethyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman and Hall Ltd 1987

Authors and Affiliations

  • Whei-Lu Kwik
    • 1
  • Kok-Peng Ang
    • 1
  1. 1.Department of ChemistryNational University of SingaporeSingaporeRepublic of Singapore

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