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Cationic rhodium(I) and iridium(I, III) complexes of cinnamonitrile and their catalytic activities

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Summary

Reactions of cinnamonitrile (trans-PhCH=CHCN) with [M(ClO4)(CO)(PPh3)2] (M=Rh or Ir) produce hydrogenation oftrans-PhCH=CHCN to PhCH2CH2CN at 100°C under 3 atm of hydrogen.

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Authors and Affiliations

  1. Department of Chemistry, Sogang University, CPO Box 1142, 121, Seoul, Korea

    Kyung Joon Yang, In Bum Kim & Chong Shik Chin

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  1. Kyung Joon Yang
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  2. In Bum Kim
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  3. Chong Shik Chin
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Yang, K.J., Kim, I.B. & Chin, C.S. Cationic rhodium(I) and iridium(I, III) complexes of cinnamonitrile and their catalytic activities. Transition Met Chem 12, 45–49 (1987). https://doi.org/10.1007/BF01023130

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  • DOI: https://doi.org/10.1007/BF01023130

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