Summary
Reactions of Group VIII metal halides [CoCl2, NiCl2, K2PdCl4, PdCl2(PhCN)2 and PtCl2] with tetrasulphurtetranitrogendioxide, S4N4O2, have been investigated. The cobalt reaction yields Co(S2N2H)2, Co(S2N2H)(S3N) and Co(S3N)2. The usefulness of metal centres for trapping reactive sulphur-nitrogen centres is discussed.
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Burgess, J.C., Tatar, Z.E. & Woollins, J.D. The preparation of cobalt complexes containing simple sulphur-nitrogen ligands, S2N2H− and S3N−, from S4N4O2 . Transition Met Chem 12, 8–9 (1987). https://doi.org/10.1007/BF01023118
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DOI: https://doi.org/10.1007/BF01023118