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Aspects of the inorganic chemistry of rubber vulcanization. Part 61 Compounds of benzothiazole-2-selenone; a selenium-containing analogue of 2-mercaptobenzothiazole

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Summary

Benzothiazole-2-selenone, BTSeH, was prepared by treating 2-chlorobenzothiazole with Na2Se, and the 6-ethoxy analogue (EtOBTSeH) was obtained similarly. From BTSeH, the species [R4N][BTSe] (R=Me, Et Bu-n), Zn-(BTSe)2(pyr)2, (BTSe−)2, Zn(BTSe-)2I2 and Me2C=CH-CH(SSeTB)Me were obtained. Addition of [n-Bu4N] [BTSe] to [Zn(BTSe)2] n afforded [n-Bu4N] [Zn(BTSe)3(H2O)]. The Se n.m.r. spectra of these species are briefly reported.

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Authors and Affiliations

  1. Department of Chemistry, University of Birmingham, PO Box 363, B15 2TT, Birmingham, UK

    Jon A. McCleverty

  2. Department of Chemistry, University of Sheffield, S3 7HF, Sheffield, UK

    Neil Spencer

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  1. Jon A. McCleverty
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  2. Neil Spencer
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McCleverty, J.A., Spencer, N. Aspects of the inorganic chemistry of rubber vulcanization. Part 61 Compounds of benzothiazole-2-selenone; a selenium-containing analogue of 2-mercaptobenzothiazole. Transition Met Chem 12, 4–8 (1987). https://doi.org/10.1007/BF01023117

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  • DOI: https://doi.org/10.1007/BF01023117

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