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Bis(2,4,6-trifluorophenyl) derivatives of palladium(II)

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Summary

The organopalladium(II) complexes: Pd(2,4,6-C6F3H2)2L2 [L=triphenylphosphine(PPh3), methyldiphenylphosphine(PPh2Me), dimethylphenylphosphine-(PPhMe2) or pyridine(py); L2=1,2-bis(diphenylphosphino)ethane(dpe), 2,2′-bipyridine(bipy), 1, 10-phenanthroline(phen) or ethylenediamine(en)] have been prepared by addition of the appropriate compound to the THF-dioxane solution resulting from the arylation of potassium tetrachloropalladate(II) with (2,4,6-C6F3H2)MgBr. The i.r. data suggest that the py and PPhMe2 compounds are thecis-isomers, whereas the PPh3 and PPh2Me compounds have thetrans configuration.1H- and19F-n.m.r. data for the compounds are reported.

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References

  1. C. F. Smith and C. Tamborski,J. Organometal. Chem.,32, 257 (1971).

    Google Scholar 

  2. G. López, G. Garcia, C. de Haro, G. Sánchez and M. C. Vallejo,J. Organometal. Chem.,263, 247 (1984).

    Google Scholar 

  3. G. Garcia, G. López and M. D. Santana,An. Quim.,79B, 214 (1983).

    Google Scholar 

  4. G. García, G. López, G. Sánchez and M. D. Santana,An. Quim.,79B, 557 (1983).

    Google Scholar 

  5. I. López, J. Martinez and M. Hernández,Talanta,33, 411 (1986).

    Google Scholar 

  6. S. E. Livingstone,Syn. React. metal-Org. Chem.,1, 1 (1971).

    Google Scholar 

  7. G. García and G. López,Inorg. Chim. Acta,52, 87 (1981).

    Google Scholar 

  8. R. Usón, A. Laguna, J. García, M. Laguna,Inorg. Chim. Acta,37, 201 (1979).

    Google Scholar 

  9. S. H. Mastin,Inorg. Chem.,13, 1003 (1974).

    Google Scholar 

  10. G. B. Deacon and I. L. Grayson,Transition Met. Chem.,8, 131 (1983).

    Google Scholar 

  11. G. B. Deacon and J. H. S. Green,Spectrochim. Acta,24A, 845 (1968).

    Google Scholar 

  12. J. R. Durig, B. R. Mitchell, D. W. Sink, J. N. Willis, Jr and A. S. Wilson,Spectrochim. Acta,23A, 1121 (1967).

    Google Scholar 

  13. J. R. Ferraro and N. R. Walker,Inorg. Chem.,4, 1382 (1965).

    Google Scholar 

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Authors and Affiliations

  1. Departamento de Qu''imica Inorgánica, Facultad de Ciencias, Universidad de Murcia, 30001, Murcia, Spain

    Gregorio López, María D. Santana, Gabriel García, Gregorio Sánchez & Joaquín García

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  1. Gregorio López
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  2. María D. Santana
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  3. Gabriel García
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  4. Gregorio Sánchez
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  5. Joaquín García
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López, G., Santana, M.D., García, G. et al. Bis(2,4,6-trifluorophenyl) derivatives of palladium(II). Transition Met Chem 12, 130–133 (1987). https://doi.org/10.1007/BF01022339

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  • DOI: https://doi.org/10.1007/BF01022339

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