Abstract
Kinetic and morphological properties of surface layers formed on the Li anode during storage in SOCl2/LiAlCl4 solution have been investigated. The synergetic effect of SO2 and LiAl(SO3Cl)4, used for voltage delay alleviation, changes the shape and size of the microcrystals of LiCl constituting the surface layer. It also leads to separate and modify the conduction and charge transfer processes involved in the kinetic properties of the surface layer at the equilibrium potential. These properties appear to be similar to those of a polycrystalline solid electrolyte where the grain boundaries induce an intergranular conduction process.
Similar content being viewed by others
References
J. P. Gabano, French Patent 7004833 (1970).
A. N. Dey,Thin Solid Films 43 (1977) 131.
E. Peled,J. Electrochem. Soc. 126 (1979) 2047.
G. L. Holleck and K. D. Brady, in Proc. Symp. on ‘Lithium Batteries’ (edited by A. N. Dey), The Electrochem. Soc. (1984).
W. Bowden, J. S. Miller, D. Cubbison and A. N. Dey,J. Electrochem. Soc. 131 (1984) 1768.
A. N. Dey and J. Miller,J. Electrochem. Soc. 126 (1979) 1445.
N. A. Fleischer and R. J. Ekern,J. Power Sources 10 (1983) 179.
D. L. Chua, W. C. Merz and W. S. Bishop, in Proc.of 27th Power Sources Symp., Atlantic City (1976).
J. P. Gabano and J. Y. Grassien, U.S. Patent 4228229 (1980).
D. Vallin and P. Chenebault, in Proc. of 32th Power Sources Symp., Cherry Hill (1986).
T. Kalmoki-Kis, U.S., Patent 4278741 (1981).
C. R. Schlaikier, in ‘Lithium Batteries’ (edited by J. P. Gabano), Academic Press, New York (1983).
J. W. Boyd,J. Electrochem. Soc. 134 (1987) 18.
M. Drache, Ph.D. Thesis, Lille, France (1979).
B. Vandorpe and M. Drache,Bull. Soc. Chim. Fr. 8 (1971) 2878.
M. Drache, B. Vandorpe and J. Heubel,Bull. Soc. Chim. Fr. 11/12 (1976) 1749.
M. Garreau and J. Thevenin,J. Microsc. Speetr. Electron. 3 (1978) 27.
P. Chenebault, Ph.D. Thesis, Paris, France (1986).
M. Bienfait, R. Boistelle and R. Kern, in ‘Adsorption et Croissance Cristalline’. Colloques Internationaux du C.N.R.S., No. 152, Nancy, France (1965) pp. 515, 577.
E. Peled, in ‘Lithium Batteries’ (edited by J. P. Gabano), Academic Press, New York (1983).
W. I. Archer and R. D. Armstrong, in ‘Electrochemistry, Vol. 7’ (edited by H. R. Thirsk), Specialist Periodical Reports. The Chemical Society, Burlington House (1978).
E. J. Schouler, N. Meshahi and G. Vitter,Solid State Ionics 9/10 (1983) 673.
H. J. de Bruin and A. D. Franklin,J. Electroanal. Chem. 118 (1981) 405.
E. Peled and H. Straze,J. Electrochem. Soc. 124 (1977) 1030.
E. Peled and H. Yamin, in Proc. of 28th Power Sources Symp., Atlantic City (1979).
R. V. Moshtev, Y. Geronov and B. Puresheva,J. Electrochem. Soc. 128 (1981) 1851.
A. M. Hermann, in Proc. Symp. on ‘Lithium Batteries’ (edited by V. H. Venkatasety), The Electrochem. Soc. (1981).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Chenebault, P., Vallin, D., Thevenin, J. et al. Properties of surface layers formed on lithium in Li-SOCl2 cells: synergetic effect of SO2 and LiAl(SO3Cl)4 . J Appl Electrochem 18, 625–632 (1988). https://doi.org/10.1007/BF01022261
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01022261