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The quadrupole interaction of100Rh in various intermetallic compounds of palladium

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Abstract

The nuclear quadrupole interaction of the 75 keV excited state of100Rh in the ordered intermetallic compounds PdHg, PdPb2 PdSb and PdTe was measured. Using an estimate for the nuclear quadrupole moment of the 75 keV state in100Rh and point ion lattice sums for the lattice electric field gradient (EFG) at the Rh site, the electronic contributionV elzz to the total EFG was derived.V elzz was found to be correlated with the average valence electron concentration in the compounds studied. In the case of PdPb2, the temperature dependence of the quadrupole interaction was also studied and found not to follow theT 3/2 rule which is observed in virtually all pure noncubic metals.

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Author notes

  1. R. Vianden (Resident Visitor at Bell Laboratories)

    Present address: Institut für Strahlen-und Kernphysik, Universität Bonn, 5300, Bonn, West-Germany

  2. G. Schmidt

    Present address: Institut für Experimentelle Kernphysik, Universität Karlsruhe, 7500, Karlsruhe, West-Germany

Authors and Affiliations

  1. Bell Laboratories, 07974, Murray Hill, New Jersey, USA

    R. Vianden (Resident Visitor at Bell Laboratories), E. N. Kaufmann & G. Schmidt

  2. Department of Physics and Chemistry, Princeton University, 08540, Princeton, New Jersey, USA

    R. A. Naumann

Authors
  1. R. Vianden
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  2. E. N. Kaufmann
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  3. R. A. Naumann
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  4. G. Schmidt
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Additional information

Work partially supported by U.S. Department of Energy.

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Vianden, R., Kaufmann, E.N., Naumann, R.A. et al. The quadrupole interaction of100Rh in various intermetallic compounds of palladium. Hyperfine Interact 7, 247–252 (1979). https://doi.org/10.1007/BF01021507

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  • DOI: https://doi.org/10.1007/BF01021507

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