Abstract
The influence of the chemical structure on the electron capture radioactive decay rate of71Ge was observed.71Ge nuclei in bivalent sulphide GeS decay faster than in quadrivalent sulphide GeS2. The relative change Δλ/λ of the decay constant λ is+(11.4±1.7) · 10−4.
A possibility to use the experimental values of Δλ/λ to determine the chemical changes in the electron density at germanium nuclei in germanium chemical compounds is discussed. Quantitative determination of the changes in the electron density is complicated because of insufficient reliability of the published values of exchange and overlap corrections to the electron capture probabilities.
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References
G.T. Emery, Ann Rev. Nucl. Sci. 22 (1972) 165.
K.-P. Dostal, M. Nagel and D. Pabst, Z. Naturforsch. 32a (1977) 345.
Nuclear Level SchemesA=45 throughA=257 from Nuclear Data Sheets. ed. Nuclear Data Group (Academic Press, New York and London, 1973).
St. Gagneux, P. Huber, H. Leuenberger and P. Nyikos, Helv. Phys. Acta 43 (1970) 39.
K. Makariūnas, Liet. Fiz. Rinkinys 18 (1978) 781.
W. Bambynek, H. Behrens, M.H. Chen, B. Crasemann, M.L. Fitzpatrick, K.V.D. Ledingham, H. Genz, M. Mutterer and R.L. Intemann, Rev. Mod. Phys. 49 (1977) 77.
K. Makariūnas, E. Makariūniené, A. Dragūnas, Proc. Int. Conf. on Mössbauer spectroscopy, Bucharest, 1977 ed. D; Barb and D. Tarina, vol. 1, p. 183.
K. Makariūnas, E. Makariūniené and A. Dragūnas, Liet. Fiz. Rinkinys 18 (1978) 45.
S.L. Ruby, G.M. Kalvius, G.B. Beard and R.E. Snyder, Phys. Rev. 159 (1967) 239.
J.K. Lees, P.A. Flinn, J. Chem. Phys. 48 (1968) 882.
K. Alder, J. Hadermann and U. Raff, Phys. Lett. 30A (1969) 487.
K. Makariūnas, Proc. Int. Conf. on Mössbauer spectroscopy, Cracow, 1975, ed. A. Hrynkiewicz and J.A. Sawicki, vol. 1, p. 495.
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Makariūnas, K., Makariūniené, E. & Dragūnas, A. Effect of chemical structure on the radioactive decay rate of71Ge. Hyperfine Interact 7, 201–205 (1979). https://doi.org/10.1007/BF01021502
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DOI: https://doi.org/10.1007/BF01021502