Journal of Applied Electrochemistry

, Volume 20, Issue 6, pp 989–995 | Cite as

Electrochemical polymerization of N-methyl-10,10-dimethylphenazasiline

  • G. Casalbore Miceli
  • G. Beggiato
  • S. S. Emmi
  • A. Geri
  • S. Daolio
  • L. Favaretto
  • D. Pietropaolo
Papers

Abstract

N-methyl-10,10-dimethylphenazasiline (SIN) was polymerized by electrochemical oxidation at +1.3 V in methylene chloride. Acid-base equilibria in solution between the heterocyclic nitrogen and the protons produced by the coupling reaction were detected. The oxidized polymer deposits on platinum or ITO electrodes to give strongly adherent and electrochromic coatings.

Keywords

Oxidation Nitrogen Polymer Methylene Chloride 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. [1]
    R. J. Waltman, A. F. Diaz and J. Bargon,J. Phys. Chem. 88 (1984) 4343.Google Scholar
  2. [2]
    J. E. Dubois, A. Desbene-Movernay and P. C. Lacaze,J. Electroanal. Chem. 132 (1982) 1773.Google Scholar
  3. [3]
    G. Casalbore Miceli, G. Beggiato, P. G. Di Marco, S. S. Emmi and G. Giro,Synth. Met. 15 (1986) 1.Google Scholar
  4. [4]
    G. Casalbore Miceli, G. Beggiato, S. Daolio, P. G. Di Marco, S. S. Emmi and G. Giro,J. Appl. Electrochem. 17 (1987) 1111.Google Scholar
  5. [5]
    G. Casalbore Miceli, G. Beggiato, S. S. Emmi, A. Geri and S. Daolio,18 (1988) 885.Google Scholar
  6. [6]
    G. Giro, G. Beggiato, G. Casalbore Miceli, P. G. Di Marco and S. S. Emmi,Mol. Cryst. Liq. Cryst. Inc. Nonlin. Opt. 156 (1988) 311.Google Scholar
  7. [7]
    D. Wassermann, R. E. Jones, S. A. Robinson and S. D. Gardner,J. Org. Chem. 30 (1965) 3248.Google Scholar
  8. [8]
    G. Innorta, S. Torrni, G. Distefano, D. Pietropaolo and A. Ricci,Org. Mass Spec. 12 (1977) 766.Google Scholar
  9. [9]
    G. Beggiato, G. Casalbore Miccli, S. S. Emmi, P. G. Di Marco, G. Giro and G. Poggi,Bull. Soc. Chim. (1988) 301.Google Scholar
  10. [10]
    B. Puduszek and M. K. Kalinowski,Electrochim. Acta 28 (1983) 639.Google Scholar
  11. [11]
    M. Opallo and A. Kapturkiewicz,30 (1985) 1301.Google Scholar
  12. [12]
    S. S. Emmi, G. Beggiato, G. Casalbore Miceli and D. Pietropaolo, unpublished observations.Google Scholar
  13. [13]
    G. Casalbore Miceli, G. Beggiato, S. Daolio, P. G. Di Marco, S. S. Emmi and G. Giro,Ann. Chim. (Rome) 77 (1987) 609.Google Scholar
  14. [14]
    G. Casalbore Miceli, G. Beggiato, S. S. Emmi, A. Geri, B. Righetti and S. Daolio,J. Chem. Soc. Perkin Trans. II (1988) 1231.Google Scholar
  15. [15]
    G. Mengoli, M. M. Musiani, G. Zotti,J. Electroanal Chem. 175 (1984) 93.Google Scholar
  16. [16]
    J. Cauquis, A. Deronzier, J.-L. Lepage, D. Serve,Bull. Soc. Chim. (1977) 295.Google Scholar
  17. [17]
    Idem G. Mengoli, M. M. Musiani, G. Zotti,ibid.J. Electroanal Chem. (1977) 303.Google Scholar

Copyright information

© Chapman and Hall Ltd. 1990

Authors and Affiliations

  • G. Casalbore Miceli
    • 1
  • G. Beggiato
    • 1
  • S. S. Emmi
    • 1
  • A. Geri
    • 1
  • S. Daolio
    • 2
  • L. Favaretto
    • 3
  • D. Pietropaolo
    • 3
  1. 1.Istituto di Fotochimica e Radiazioni d'Alta Energia del Consiglio Nazionale delle RicercheBolognaItaly
  2. 2.Istituto di Polarografia ed Elettrochimica Preparativa del Consiglio Nazionale delle RicerchePadovaItaly
  3. 3.Istituto dei Composti del Carbonio Contenenti Eteroatomi e loro ApplicazioniBolognaItaly

Personalised recommendations