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An inequality for partition functions with disturbed Hamiltonians

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Abstract

We consider a thermodynamic system consisting ofn independent subsystems. Each subsystem is described by a HamiltonianH=H 0+α i H 1,i=1, 2,...,n. We answer the question of how the entiretyα=(α 1,α 2,...,α n) must be varied in order to change the total partition function and the total free energy of the system monotonically.

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Zylka, C. An inequality for partition functions with disturbed Hamiltonians. J Stat Phys 60, 281–284 (1990). https://doi.org/10.1007/BF01013679

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  • DOI: https://doi.org/10.1007/BF01013679

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