Abstract
The phonon responses along the three crystallographic orientations of KH2PO4, 90% deuterated K(H1−xDx)2 PO4 and NH4H2PO4, deduced from the best fit of the factorised form of the dielectric function to the infrared reflectivity spectra, are compared. Results evidence the activity of a low-frequency heavily damped extra-mode in both directions parallel and perpendicular to the c axis, due to the coupling of an internal mode with the inter-site protonic motion and external models.
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Brehat, F., Wyncke, B. Low-frequency models in KH2PO4-type crystals. Int J Infrared Milli Waves 8, 155–176 (1987). https://doi.org/10.1007/BF01012551
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DOI: https://doi.org/10.1007/BF01012551