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Journal of Statistical Physics

, Volume 12, Issue 3, pp 167–204 | Cite as

Statistical transport theory of reacting two-component fluid: Light scattering from an A⇄B liquid

  • Paul Madden
  • Daniel Kivelson
Articles

Abstract

A theory of light scattering from a simple A⇄B reacting fluid in which molecular anisotropy has been neglected is presented. The theory is a molecular-statistical one based on Mori's linear response formalism. The time-dependent correlation functions are associated with transport coefficients and the zero time correlation functions are associated with thermodynamic derivatives. The effects of the reaction are observed from both density and concentration fluctuations as well as from cross correlations between density and concentration fluctuations.

Key words

Light scattering reacting solutions transport theory 

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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • Paul Madden
    • 1
    • 2
  • Daniel Kivelson
    • 1
    • 3
  1. 1.Department of ChemistryUniversity of CaliforniaLos Angeles
  2. 2.School of Molecular ScienceUniversity of SussexBrightonEngland
  3. 3.Department of Chemical EngineeringImperial CollegeLondonEngland

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