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Stochastic theory of adiabatic explosion

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Abstract

A stochastic description of an exothermic reaction leading to adiabatic explosion is set up. The numerical solution of the master equation reveals the appearance of a long tail and of multiple humps of the probability distribution, which subsist for a certain period of time. During this interval the system displays a markedly chaotic behavior, reflecting the random character of the ignition process. An analytical description of this transient evolution is developed, using a piecewise linear approximation of the transition rates. A comparison with other transient phenomena observed in stochastic theory is carried out.

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References

  1. P. Gray, inNonlinear Phenomena in Chemical Dynamics, A. Pacault and C. Vidal, eds. (Springer-Verlag, Berlin, 1981).

    Google Scholar 

  2. G. Joulin and P. Clavin,Comb. Flame 35:139 (1979).

    Google Scholar 

  3. D. A. Frank-Kamenetski,Diffusion and Heat Transfer in Chemical Kinetics (Plenum, New York, 1969).

    Google Scholar 

  4. G. Nicolis and I. Prigogine,Self-Organization in Nonequilibrium Systems (Wiley, New York, 1977).

    Google Scholar 

  5. G. Nicolis, F. Baras, and M. Malek Mansour,Nonlinear Phenomena in Chemical Dynamics, A. Pacault and C. Vidal, eds. (Springer-Verlag, Berlin, 1981).

    Google Scholar 

  6. V. N. Kondratiev and E. E. Nikitin,Gas-Phase Reactions (Springer-Verlag, Berlin, 1981).

    Google Scholar 

  7. D. R. Kassoy,Comb. Sci. Tech. 10:27 (1975);Q. J. Mech. Appl. Math. 30:71 (1977); D. R. Kassoy and A. Linan,Ibid. 31:99 (1978).

    Google Scholar 

  8. Nonlinear Phenomena in Chemical Dynamics, A. Pacault and C. Vidal, eds. (Springer-Verlag, Berlin, 1981).

    Google Scholar 

  9. S. Karlin and H. M. Taylor,A First Course in Stochastic Processes (Academic Press, New York, 1975).

    Google Scholar 

  10. N. Goel and N. Richter-Dyn,Stochastic Models in Biology (Academic Press, New York, 1974).

    Google Scholar 

  11. A. K. Kapila,SIAM J. Appl. Math. 39:21 (1980).

    Google Scholar 

  12. R. Kubo, K. Matsuo, and K. Kitahara,J. Stat. Phys. 9:51 (1973).

    Google Scholar 

  13. M. Frankowicz and M. Malek Mansour (to be published).

  14. M. Frankowicz and G. Nicolis,J. Stat. Phys. (submitted).

  15. J. W. Turner (to be published).

  16. T. Kurtz,Stock. Proc. Applic. 6:223 (1978).

    Google Scholar 

  17. M. Suzuki, inProc. XVIIth Solvay Conf. Phys. (Wiley, New York, 1981).

    Google Scholar 

  18. N. G. Van Kampen,J. Stat. Phys. 17:71 (1977).

    Google Scholar 

  19. B. Caroli, C. Caroli, and B. Roulet,J. Stat. Phys. 21:415 (1979);Physica 101A:581 (1980).

    Google Scholar 

  20. L. Arnold, W. Horsthemke, and R. Lefever,Z. Phys. B29:367 (1978); R. Lefever and W. Horsthemke,Proc. Natl. Acad. Sci. USA 76:2490 (1979).

    Google Scholar 

  21. M. Eigen and P. Schuster,The Hypercycle (Springer-Verlag, Berlin, 1979).

    Google Scholar 

  22. I. Prigogine, G. Nicolis, and A. Babloyanz,Phys. Today 25(11):23;12:38 (1972).

    Google Scholar 

  23. A. Goldbeter and L. A. Segel,Differentiation 17:127 (1980).

    Google Scholar 

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Boursier I.R.S.I.A.

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Baras, F., Nicolis, G., Mansour, M.M. et al. Stochastic theory of adiabatic explosion. J Stat Phys 32, 1–23 (1983). https://doi.org/10.1007/BF01009416

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  • DOI: https://doi.org/10.1007/BF01009416

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